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Benzene is treated with isobutyl al...

Benzene is treated with isobutyl alcohol in presence of conc. `H_(2)SO_(4)`

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In presence of conc. `H_(2)SO_(4)` , isobutyl alcohol first generates a `1^(@)` carbocation which then undergoes rearrangement by 1,2-hydride shift to form a more stable tert-butyl carbocation. This subsequently reacts with benzene to form tert-butylbezene.
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Name the final product of the following reactions : (i) Benzene is treated with methyl chloride in presence of anhydrous aluminium chloride. (ii) Benzene is treated with acetyl chloride in the presence of anhydrous aluminium chloride. (iii) Phenol is heated with zinc. (iv) Sodium benzoate is heated with soda lime. (v) Benzene is treated with fumining nitric acid in presence of conc. H_(2)SO_(4) . (vi) Benzene is catalytically hydrogenated. (vii) Ozone reacts with benzene. (viii) Toluene is treated with a mixture of conc. CNO_(3) and conc. H_(2)SO_(4) . (ix) Chlorine is passed through boiling toluene. (x) Toluene is heated with acidic potassium premanganate solution. (xi) Toluene in carbon tetrachloride is oxidised by chromyl chloride. (xii) Ortho-xylene is oxidised with hot acidic K_(2)Cr_(2)O_(7) solution.

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Knowledge Check

  • Nitration of benzene is carried out with conc. HNO_(3) in presence of conc. H_(2)SO_(4) . The role of conc. H_(2)SO_(4) is to provide

    A
    nucleophile during the reaction
    B
    free radical during the reaction
    C
    electrophile during the reaction
    D
    catalyst during the reaction
  • Phenol when nitrated with conc. HNO_(3) in presence of conc. H_(2)SO_(4) forms

    A
    o-nitrophenol
    B
    m-nitrophenol
    C
    p-nitrophenol
    D
    picric acid
  • Benzene on reaction with conc. HNO_(3) in presence of conc. H_(2)SO_(4) followed by the treatment of CI_(2) in presence of FeCI_(3) followed by the treatment of CI_(2) in presence of FeCI_(3) , it gives :

    A
    2-chloro-1-nitrobenzene
    B
    3-chloro-1-nitrobenzene
    C
    4-chloro-nitrobenzene
    D
    a maxture of 1-chloro and 4-chloro-1-nitrobenzene
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