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White phosphorus P(4) has the following ...

White phosphorus `P_(4)` has the following characteristics.

A

6 P-P single bond

B

4 P-P single bonds

C

4 lone pair of electrons

D

P-P-P angle of `60^(@)`

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To analyze the characteristics of white phosphorus (P₄), we can break down the information step by step: ### Step 1: Understand the Structure of White Phosphorus (P₄) White phosphorus consists of four phosphorus atoms arranged in a tetrahedral structure. Each phosphorus atom is bonded to three other phosphorus atoms through single covalent bonds. **Hint:** Remember that the tetrahedral structure is a key feature of P₄, where each phosphorus atom is connected to three others. ### Step 2: Determine the Valence Electrons Phosphorus has an atomic number of 15, which means it has 15 electrons. The electronic configuration is 2, 8, 5. The 5 electrons in the outermost shell (valence shell) are crucial for bonding. **Hint:** Focus on the valence electrons, as they determine how phosphorus atoms bond with each other. ### Step 3: Analyze the Bonding In P₄, each phosphorus atom shares its three valence electrons with three neighboring phosphorus atoms, forming single covalent bonds. This sharing allows each phosphorus atom to achieve a stable octet configuration. **Hint:** Consider how covalent bonding occurs through the sharing of electrons to complete the octet. ### Step 4: Count the Bonds In the tetrahedral structure of P₄, there are a total of 6 P-P single bonds formed between the phosphorus atoms. **Hint:** Keep track of how many bonds are formed in the structure; this is essential for understanding the connectivity of the atoms. ### Step 5: Identify Lone Pairs Each phosphorus atom in P₄ has one lone pair of electrons. Since there are four phosphorus atoms, there are a total of 4 lone pairs in the molecule. **Hint:** Remember that lone pairs are unshared pairs of electrons that can influence the geometry of the molecule. ### Step 6: Determine the Bond Angles The bond angles between the P-P-P bonds in white phosphorus are approximately 60 degrees due to the tetrahedral arrangement of the atoms. **Hint:** Bond angles are important in understanding the spatial arrangement of atoms in a molecule. ### Conclusion Based on the analysis: - There are 6 P-P single bonds. - There are 4 lone pairs of electrons. - The bond angle is approximately 60 degrees. Thus, the correct characteristics of white phosphorus (P₄) include: - 6 P-P single bonds (correct) - 4 lone pairs of electrons (correct) - P-P-P bond angle of 60 degrees (correct) ### Final Answer The correct characteristics of white phosphorus (P₄) are A, C, and D.

To analyze the characteristics of white phosphorus (P₄), we can break down the information step by step: ### Step 1: Understand the Structure of White Phosphorus (P₄) White phosphorus consists of four phosphorus atoms arranged in a tetrahedral structure. Each phosphorus atom is bonded to three other phosphorus atoms through single covalent bonds. **Hint:** Remember that the tetrahedral structure is a key feature of P₄, where each phosphorus atom is connected to three others. ### Step 2: Determine the Valence Electrons ...
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Knowledge Check

  • White phosphorus is

    A
    A monoatomic gas
    B
    `P_(4)`, a tetrahedral solid
    C
    `P_(8)`, a crown
    D
    A linear diatomic molecules
  • White phosphorus has.

    A
    Six `P-P` single bonds
    B
    Four `P-P` single bonds
    C
    Four lone pairs of electrons
    D
    `P-P-P` angle of `60^@`.
  • White phosphorus (P_4) does not contain

    A
    six P-P single bonds
    B
    four P-P single bonds
    C
    four lone pairs of electrons
    D
    P-P-P angle of `60^@`
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