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At what pH of HCl solution, will hydroge...

At what pH of HCl solution, will hydrogen gas electrode show electrode potential of -0.118 V ? `H_(2)` gas is bubbled at 298 K and 1 atm pressure.

Text Solution

Verified by Experts

Writing electrode reaction as reduction reaction, `H^(+)+e^(-)to(1)/(2)H_(2)`
Applying nernst equation, `E_(H^(+)//H_(2))=E_(H^(+)//H_(2))^(@)-(0.0591)/(1)"log"(1)/([H^(+)])=0+0.0591log[H^(+)]`
or `-0.118=-0.0591pH` or `pH=2` (`becausepH=-log[H^(+)])`
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Knowledge Check

  • The potential of a hydrogen electrode at pH = 1 will be:

    A
    `–0.059` Volt
    B
    `0.00` Volt
    C
    `-0.24` Volt
    D
    `-0.59` Volt
  • Electrode potential of hydrogen electrode is 18 m V then [H^(+)] is -

    A
    `0.2`
    B
    `1`
    C
    2
    D
    5
  • The value of E_("cell") of hydrogen electrode at pH=0 298 K and 1 atm, is

    A
    0.59 V
    B
    0 V
    C
    `-0.59 V`
    D
    `-0.059 V`
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