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How is the variability in oxidation stat...

How is the variability in oxidation states fo transition metals different from that of the non transition metaals?
Illustrate with examples.

Text Solution

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The variability in oxidation states of transition metals is due to the incomplete filling of d-orbitals in such a way that their oxidation states differ from each other by unity, e.g., `Fe^(2+)` and `Fe^(3+), Cu^(+)` and `Cu^(2+)` and `Cu^(2+)` etc. In case of non-transition elements, the oxidation states differ by units of two , e.g., `Pb^(2+)` and `Pb^(4+), Sn^(2+)` and `Sn^(4+)` etc. Moreover , in transition elements, the higher oxidation states are more stable for heavier elements in a group. For example , in group 6, Mo(VI) and W(VI) are more stable than Cr(VI) . In p-block elements , the lower oxidation states are more stable for heavier members due to inert pair effect, e.g., in group 16, Pb (II) is more stable than Pb(IV).
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Knowledge Check

  • The variability of oxidation states of transition elements arises out of:

    A
    incomplete filling of d-orbitals
    B
    oxidation states differing by a unit two
    C
    greater stability of lower oxidation state
    D
    greater stability of higher oxidation state
  • The common oxidation state of transition elements is

    A
    `+2`
    B
    `+4`
    C
    `+3`
    D
    `+7`
  • In which pair highest oxidation states of transition metals are found

    A
    nitriles and chlorides
    B
    fluorides and chlorides
    C
    fluorides and oxides
    D
    nitriles and oxides
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    Lower oxidation state in transition metals are stabilized by

    The maximum oxidation state of transition metals are obtained by the following: