Home
Class 12
CHEMISTRY
How is the variability in oxidation stat...

How is the variability in oxidation states fo transition metals different from that of the non transition metaals?
Illustrate with examples.

Text Solution

Verified by Experts

The variability in oxidation states of transition metals is due to the incomplete filling of d-orbitals in such a way that their oxidation states differ from each other by unity, e.g., `Fe^(2+)` and `Fe^(3+), Cu^(+)` and `Cu^(2+)` and `Cu^(2+)` etc. In case of non-transition elements, the oxidation states differ by units of two , e.g., `Pb^(2+)` and `Pb^(4+), Sn^(2+)` and `Sn^(4+)` etc. Moreover , in transition elements, the higher oxidation states are more stable for heavier elements in a group. For example , in group 6, Mo(VI) and W(VI) are more stable than Cr(VI) . In p-block elements , the lower oxidation states are more stable for heavier members due to inert pair effect, e.g., in group 16, Pb (II) is more stable than Pb(IV).
Promotional Banner

Topper's Solved these Questions

  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise NCERT (QUESTIONS AND EXERCISES WITH ANSERS)|10 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise NCERT INTEXT UNSOLVED QUESTIONS|10 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise TEST YOUR GRIP( FILL IN THE BLANKS)|33 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Important Questions|28 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|25 Videos

Similar Questions

Explore conceptually related problems

How is the variablility in oxidation states of transition metals different from that of the non transition metals gt illustrate with example

How is the variability in oxidation state of transition metals different from these of p-block elements ?

The variability of oxidation states of transition elements arises out of:

In What way is the electronic configuration of the transition elements different from the of the non-transition elements?

The maximum oxidation state of transition metals are obtained by the following:

PRADEEP-D- AND F-BLOCK ELEMENTS-CONCEPTUAL QUESTIONS
  1. The E^(@) value in respect of the electrodes (Z=24), manganese (Z=25) ...

    Text Solution

    |

  2. Why do transition elements show variable oxidation state?

    Text Solution

    |

  3. How is the variability in oxidation states fo transition metals differ...

    Text Solution

    |

  4. Among lanthanoids, Ln (III) compounds are predominant. However, occasi...

    Text Solution

    |

  5. How would you account for the fact that the transition metals and thei...

    Text Solution

    |

  6. Why generally there is an increase in density of elements from titani...

    Text Solution

    |

  7. Giving reasons indicate which one of the following would be coloured ?...

    Text Solution

    |

  8. Scandium forms no coloured ions, yet it is regarded as a transition el...

    Text Solution

    |

  9. A substance is found to have a magnetic moments of 3.9BM.How many unpa...

    Text Solution

    |

  10. The paramagnetic character in 3d transition series elements increases ...

    Text Solution

    |

  11. Decide giving reason which one of the following pairs exhibits the pr...

    Text Solution

    |

  12. (a) of the ions Ag^(+),Co^(2+) and Ti^(+), which one will be coloured ...

    Text Solution

    |

  13. Why are the ionisation energies of 5d elements greater than 3d element...

    Text Solution

    |

  14. Describe giving reason which one of the following pairs has the proper...

    Text Solution

    |

  15. Give reason for the following features of transition metal chemistry: ...

    Text Solution

    |

  16. The 4d and 5d series of transition metals have more frequency metal-me...

    Text Solution

    |

  17. Give reasons for each of the following: (i) Size of trivalent lantha...

    Text Solution

    |

  18. Assign reason for each of the following statement: (i) The largest n...

    Text Solution

    |

  19. (i) Which is a stronger reducing agent Cr^(2+) or Fe^(2+) and why ? ...

    Text Solution

    |

  20. Assign reasons for each of the following : (i) Manganese exhibits th...

    Text Solution

    |