Home
Class 12
CHEMISTRY
How would you account for the fact that ...

How would you account for the fact that actinoids exhibit a larger number of oxidation state than the corresponding lanthanoids?

Text Solution

Verified by Experts

Actinoids show a larger number of oxidation states because the energy gap between 5f, 6d and 7s subhsells is very small and hence all the electrons present in these subshells can participate in bonding whereas lanthanoids show a limited number of oxidation states because the energy gap between 4f and 5d subshells is large and all the electrons in these subshells cannot participate in bonding.
Promotional Banner

Topper's Solved these Questions

  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise NCERT (QUESTIONS AND EXERCISES WITH ANSERS)|10 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise NCERT INTEXT UNSOLVED QUESTIONS|10 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise TEST YOUR GRIP( FILL IN THE BLANKS)|33 Videos
  • CORDINATION COMPOUNDS

    PRADEEP|Exercise Important Questions|28 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise IMPORTANT QUESTIONS FOR BOARD EXAMINATION|25 Videos

Similar Questions

Explore conceptually related problems

Explain the following observations: (i) Many of the transition elements are known to form interstitial compounds. (ii) There is a general increase in density from titanium (Z = 22) to copper (Z = 29). (iii) The members of the actinoid series exhibit a larger number of oxidation states than the corresponding members of the lanthanoid series.

How would you account for the following ? (i) With the same d-orbital configuration (d^(4)) Cr^(2+) is reducting agent while Mn^(3+) is an oxidizing agent. (ii) The actionoids exhibits a larger numbe of oxidation states than the corresponding members in the lanthanoid series. (iii) Most of the transition metal ions exhibit characteristic in colours in aqueous solutions.

How will you account for the following: (a) Actinoids exhibit more number of oxidation states than lanthanoids. (b) Atomic radii of second and third transition series elements are almost identical.

The actinoids exhibit more number of oxidation states in general than the lanthanoids. This is because

The actinoids exhibit, more member of oxidation states in general than the lanthanoids. This is because

(a) Silver atom has completely filled 'd' orbitals (4d^10) in its ground state. How can you say that it is a transition element ? (b) Actinoids exhibit a large number of oxidation states in comparison to corresponding members of Lanthanoid series. Why?

Which of the following exhibit minimum number of oxidation states

PRADEEP-D- AND F-BLOCK ELEMENTS-CONCEPTUAL QUESTIONS
  1. (a) Following are the transition metal ions of 3d series: Ti^(4+),V^...

    Text Solution

    |

  2. Write the formula of different oxides of manganese. What is the oxidat...

    Text Solution

    |

  3. What is the effect of increasing pH on the colour of K(2)Cr(2)O(7) sol...

    Text Solution

    |

  4. In the titratin of Fe^(2+) ions with KMnO(4) in acidic medium, why dil...

    Text Solution

    |

  5. Give the relationship between the equivalent weight and molecular weig...

    Text Solution

    |

  6. Why is it not advisable to dissolve KMnO(4) in conc. H(2)SO(4) ?

    Text Solution

    |

  7. Why in permanganate ion, there is a covalency between Mn and oxygen ?

    Text Solution

    |

  8. When chromite ore FeCr(2)O(4) is fuse with NaOH in presence of air, a ...

    Text Solution

    |

  9. Briefly explain why electronic configuration of lanthanoids are not kn...

    Text Solution

    |

  10. The +3 oxidation states of langthanum ( Z= 57), gadolinium (Z= 64) and...

    Text Solution

    |

  11. The outer electronic configuration of two members of the lanthanoid se...

    Text Solution

    |

  12. Why Zr and Hf or Nb and Ta exhibit similar properties? Or Zirconium ...

    Text Solution

    |

  13. Why Sm^(2+), Eu^(2+) and Yb^(2+) ions in solutions are good reducing a...

    Text Solution

    |

  14. One among the langthanides ,Ce(III), can be easily oxidized to Ce(IV)(...

    Text Solution

    |

  15. Which out of the two, La(OH)(3) and Lu(OH)(3) is more basic and why ?

    Text Solution

    |

  16. The electronic configuration of actinide elements are not known with c...

    Text Solution

    |

  17. How would you account for the fact that actinoids exhibit a larger num...

    Text Solution

    |

  18. The actinide contraction differs from lanthanide contraction ? Explai...

    Text Solution

    |

  19. Account for the following : (i) Oxidizing power in the series : VO^(...

    Text Solution

    |

  20. Account for the following : (a) Europlum (II) is more stable than ce...

    Text Solution

    |