The ratio of te shortest wavelength of two spectral series of hydrogen spectrum is found to be about 9. The spectral series are:
A
Lyman and Paschen
B
Balmer an Brackett
C
Brackett and Pfund
D
Paschen and Pfund
Text Solution
AI Generated Solution
The correct Answer is:
To solve the problem, we need to identify the two spectral series of the hydrogen spectrum based on the given ratio of the shortest wavelengths.
### Step-by-Step Solution:
1. **Understanding the Wavelength Formula**:
The wavelength (\( \lambda \)) of spectral lines in hydrogen can be calculated using the Rydberg formula:
\[
\frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right)
\]
where \( R_H \) is the Rydberg constant, \( n_1 \) is the lower energy level, and \( n_2 \) is the higher energy level.
2. **Identifying the Shortest Wavelength**:
The shortest wavelength corresponds to the transition where \( n_2 \) approaches infinity. Thus, for the shortest wavelength, the formula simplifies to:
\[
\frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} \right)
\]
This means that the shortest wavelength is inversely proportional to \( n_1^2 \).
3. **Setting Up the Ratio**:
Let’s denote the two spectral series by their lower energy levels:
- For the first series, let \( n_1 = m \).
- For the second series, let \( n_1 = n \).
The ratio of the shortest wavelengths is given as:
\[
\frac{\lambda_m}{\lambda_n} = \frac{n^2}{m^2} = 9
\]
4. **Solving the Ratio**:
From the ratio \( \frac{n^2}{m^2} = 9 \), we can take the square root of both sides:
\[
\frac{n}{m} = 3 \quad \text{or} \quad \frac{m}{n} = \frac{1}{3}
\]
This implies that \( n = 3m \).
5. **Identifying the Series**:
The possible values for \( m \) and \( n \) must correspond to the known spectral series:
- Lyman series (UV region): \( n_1 = 1 \)
- Balmer series (visible region): \( n_1 = 2 \)
- Paschen series (IR region): \( n_1 = 3 \)
- Brackett series (IR region): \( n_1 = 4 \)
If we set \( m = 1 \) (Lyman series), then \( n = 3 \) (Paschen series).
6. **Conclusion**:
The two spectral series corresponding to the given ratio of the shortest wavelengths are:
- Lyman series (for \( n_1 = 1 \))
- Paschen series (for \( n_1 = 3 \))
### Final Answer:
The spectral series are the **Lyman series** and the **Paschen series**.