Home
Class 11
CHEMISTRY
The equilibrium constant at 25^(@)C for ...

The equilibrium constant at `25^(@)C` for the process:
`CO^(3+) (aq) +6NH_(3)(aq) hArr[Co(NH_(3))_(6)]^(3+)(aq)` is `2 xx 10^(7)`.
Calculate the value of `DeltaG^(Theta)` at `25^(@)C at 25^(@)C[R = 8.314 J K^(-1)mol^(-1)]`.
In which direction the reaction is spontaneous when the recatants and proudcts are in standard state?

Text Solution

Verified by Experts

`DeltaG^(Theta)` is related to equilibrium constant, `K` as
`DeltaG^(Theta) =- 2.303 RT logK`
`DeltaG^(Theta) = ? , K = 2.0 xx 10^(7), T = 25 +273 = 298K`
`DeltaG^(Theta) =- 2.303 xx 8.314 xx 298 log 2 xx 10^(7)`
`=- 12023.4 J =- 12.023 kJ`
Since `DeltaG^(Theta)` is negative, the reactio is spontaneous in the forward direction.
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Subjective)|70 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Exercises (Linked Comprehension)|74 Videos
  • THERMODYNAMICS

    CENGAGE CHEMISTRY|Exercise Ex 6.4|16 Videos
  • STOICHIOMETRY

    CENGAGE CHEMISTRY|Exercise Archives Subjective|33 Videos
CENGAGE CHEMISTRY-THERMODYNAMICS-Ex 6.5
  1. Calculate the standard Gibbs free energy change from the free energies...

    Text Solution

    |

  2. Consider the reaction: 2NO(g)+O(2)(g) rarr 2NO(2)(g) Calculated th...

    Text Solution

    |

  3. For the water gas reaction: C(s) +H(2)O(g) hArr CO(g) +H(2)(g) the...

    Text Solution

    |

  4. Using the following data, calculate the value of equilibrium constant ...

    Text Solution

    |

  5. The equilibrium constant at 25^(@)C for the process: CO^(3+) (aq) +6...

    Text Solution

    |

  6. The standard Gibbd energies (Delta(f)S^(Theta)) for the formation of S...

    Text Solution

    |

  7. It is planned to carry out the reaction: CaCO(3)(g) hArr CaO(s) +CO(...

    Text Solution

    |

  8. The equilibrium constant for the reaction CO(2)(g) +H(2)(g) hArr CO(...

    Text Solution

    |

  9. Calculated the equilibrium constant for the following reaction at 298K...

    Text Solution

    |

  10. The equilibrium constant for the reaction: CH(3)COOH(l) +C(2)H(5)OH(...

    Text Solution

    |

  11. Calculate the entropy change for a reaction: XrarrY Given that Del...

    Text Solution

    |

  12. Calculate the equilibrium constant for the following reaction at 298K ...

    Text Solution

    |

  13. For the equilibrium reaction: 2H(2)(g) +O(2)(g) hArr 2H(2)O(l) at 29...

    Text Solution

    |

  14. Calculate the equilibrium constant for the reaction given below at 400...

    Text Solution

    |

  15. Calculate equilibrium constant for the reaction: 2SO(2)(g) +O(2)(g) ...

    Text Solution

    |

  16. C(2)H(4) +CI(2) rarr C(2)H(4)CI(2) DeltaH =- 270.6 kJ mol^(-1)K^(-1)...

    Text Solution

    |

  17. Calculate free energy change for the reaction: H(2)(g) + CI(2)(g) ra...

    Text Solution

    |

  18. For the reaction, 4C(graphite) +5H(2)(g) rarr nC(4)H(10)(g), Delt...

    Text Solution

    |

  19. A chemical reaction cannot occur at all is

    Text Solution

    |

  20. Calculate the standard free energy change for the reaction: H(2)(g)...

    Text Solution

    |