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The rate constant of a reaction depends ...

The rate constant of a reaction depends on

A

Temperature

B

Initial concentration of the reactions

C

Time of reaction

D

Extent of reaction

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The correct Answer is:
To determine what the rate constant (K) of a reaction depends on, we can analyze the factors that influence it. The rate constant is a crucial parameter in chemical kinetics and is defined by the Arrhenius equation. ### Step-by-Step Solution: 1. **Understanding the Rate Constant (K)**: The rate constant (K) is a proportionality factor in the rate law of a reaction. The general form of the rate law is given by: \[ \text{Rate} = K \cdot [A]^n \] where \([A]\) is the concentration of the reactant and \(n\) is the order of the reaction. 2. **Applying the Arrhenius Equation**: The Arrhenius equation relates the rate constant to temperature and activation energy: \[ K = A \cdot e^{-\frac{E_a}{RT}} \] where: - \(K\) = rate constant - \(A\) = pre-exponential factor (frequency factor) - \(E_a\) = activation energy - \(R\) = universal gas constant - \(T\) = temperature (in Kelvin) 3. **Analyzing the Dependence on Temperature**: From the Arrhenius equation, we can see that the rate constant \(K\) is dependent on temperature (\(T\)). As the temperature increases, the term \(-\frac{E_a}{RT}\) becomes less negative, leading to an increase in \(K\). This implies that: - Higher temperatures result in a higher rate constant. 4. **Evaluating Other Factors**: - **Concentration of Reactants**: The rate constant does not depend on the concentration of reactants. It is a characteristic of the reaction at a given temperature. - **Time of Reaction**: The rate constant is independent of the time duration of the reaction. - **Extent of Reaction**: The rate constant does not depend on how far the reaction has proceeded. 5. **Conclusion**: The rate constant \(K\) depends solely on temperature. Therefore, the correct answer is that the rate constant of a reaction depends on temperature. ### Final Answer: The rate constant of a reaction depends on temperature.

To determine what the rate constant (K) of a reaction depends on, we can analyze the factors that influence it. The rate constant is a crucial parameter in chemical kinetics and is defined by the Arrhenius equation. ### Step-by-Step Solution: 1. **Understanding the Rate Constant (K)**: The rate constant (K) is a proportionality factor in the rate law of a reaction. The general form of the rate law is given by: \[ \text{Rate} = K \cdot [A]^n ...
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Knowledge Check

  • The rate of constant of a reaction depends on

    A
    Temperature
    B
    Mass
    C
    Weight
    D
    Time
  • The specific reaction rate (or rate constant) of a reaction depends upon (i) temperature of reaction (ii) concentration of reactants and products (iii) activation energy of reaction (iv) presence of absence of a catalyst

    A
    (i), (iii), (iv)
    B
    (i), (ii), (iii), (iv)
    C
    (i), (iii)
    D
    (i), (ii)
  • The rate constant of a reaction does not depend upon:

    A
    temperture
    B
    activation energy
    C
    catalyst
    D
    concentration of reactants and products
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