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If excess of AgNO(3) solution is added t...

If excess of `AgNO_(3)` solution is added to 100mL of a 0.024 M solution of dichlorobis (ethylenediamine) cobalt (III) chloride . How many mole of AgCl be precipitated ?

A

`0.0012`

B

`0.0016`

C

`0.0024`

D

`0.0048`

Text Solution

Verified by Experts

The correct Answer is:
C

`Co^(3+) + 2 Cl^(-) + 2 (en)`
net charge = +1
Thus , complex is
`[Co(en)_(2) Cl_(2)]^(+) Cl^(-) to [Co(en)_(2) Cl_(2)]^(+) + Cl^(-)`
Only one `Cl^(-)` which is precipitated as AgCl
100 mL of 0.024 M complex = 2.4 millimol = 0.0024 mol
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Knowledge Check

  • If excess of AgNO_(3) solution is added to 100mL of a 0.024 M solution of dichlorobis (ethylene diamine) cobalt (III) chloride, how many mol of AgCl be precipitated?

    A
    0.0012
    B
    0.0016
    C
    0.0024
    D
    0.0048
  • If excess of AgNO_(3) solution is added to 100 mL of a 0.024 M solution of dichlorobis (ethylene diamine) cobalt (III) chloride, how many mol of AgCl be precipitated:

    A
    `0.0012`
    B
    `0.0016`
    C
    `0.0024`
    D
    `0.0048`
  • An excess of AgNO_3 is added to 100mL of a 0.01M solution of dichlorotetraaquachromin (III) chloride. The number of moles of AgCl precipitated would be:

    A
    (a) `0.002`
    B
    (b) `0.001`
    C
    (c) `0.003`
    D
    (d) `0.01`
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