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Which of the following does not give iod...

Which of the following does not give iodoform test?

A

`C_(2)H_(5)OH`

B

`C_(6)H_(5)OH`

C

`(CH_(3))_(2)CHOH`

D

All of these

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The correct Answer is:
To determine which compound does not give the iodoform test, we need to analyze the given options: ethyl alcohol, phenol, and isopropyl alcohol. The iodoform test is a qualitative test for the presence of methyl ketones or alcohols that can be oxidized to methyl ketones. ### Step-by-Step Solution: 1. **Understanding the Iodoform Test:** The iodoform test (also known as the haloform test) is positive for compounds that have a methyl group adjacent to a carbonyl group (methyl ketones) or compounds that can be oxidized to such structures. The general structure for these compounds is: - Methyl ketones: \( RCOCH_3 \) - Secondary alcohols that can be oxidized to methyl ketones: \( RCHOHCH_3 \) 2. **Analyzing Ethyl Alcohol (C₂H₅OH):** Ethyl alcohol (or ethanol) can be represented as \( CH_3CH_2OH \). - It does not have a methyl ketone structure or the ability to be oxidized to one. - Therefore, ethyl alcohol does **not** give a positive iodoform test. 3. **Analyzing Phenol (C₆H₅OH):** Phenol has the structure \( C_6H_5OH \). - It does not contain a methyl group adjacent to a carbonyl or can be oxidized to a methyl ketone. - Thus, phenol also does **not** give a positive iodoform test. 4. **Analyzing Isopropyl Alcohol (C₃H₇OH):** Isopropyl alcohol (or 2-propanol) can be represented as \( CH_3CHOHCH_3 \). - This compound has the structure that allows it to be oxidized to acetone (a methyl ketone), which is \( CH_3COCH_3 \). - Therefore, isopropyl alcohol does give a positive iodoform test. 5. **Conclusion:** Among the three compounds: - Ethyl alcohol does not give the iodoform test. - Phenol does not give the iodoform test. - Isopropyl alcohol does give the iodoform test. The correct answer to the question "Which of the following does not give iodoform test?" is **Phenol (C₆H₅OH)**. ### Final Answer: **Phenol (C₆H₅OH)** does not give the iodoform test.

To determine which compound does not give the iodoform test, we need to analyze the given options: ethyl alcohol, phenol, and isopropyl alcohol. The iodoform test is a qualitative test for the presence of methyl ketones or alcohols that can be oxidized to methyl ketones. ### Step-by-Step Solution: 1. **Understanding the Iodoform Test:** The iodoform test (also known as the haloform test) is positive for compounds that have a methyl group adjacent to a carbonyl group (methyl ketones) or compounds that can be oxidized to such structures. The general structure for these compounds is: - Methyl ketones: \( RCOCH_3 \) - Secondary alcohols that can be oxidized to methyl ketones: \( RCHOHCH_3 \) ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALCOHOLS, PHENOLS AND ETHERS-PRACTICE EXERCISE (Exercise 1 (TOPICAL PROBLEMS))
  1. Which of the following does not give iodoform test?

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  2. Conversion of ethyl alcohol into acetaldehyde is an example of

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  3. Catalytic dehydrogenation of a primary alcohol gives a/an

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  4. Dehydration of methyl alcohol with conc. H(2)SO(4) yields

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  5. Propene on hydroboration and oxidation produces

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  6. The alcohols, propan-1ol and propan-2-ol are distinguished by

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  7. Boiling point of alcohol is comparatively higher than that of correspo...

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  8. In the following reaction most stable intermediate is {:(" ...

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  9. Consider the following reaction, Aoverset(K(2)Cr(2)O(7))underset(H(2...

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  10. Which of the following is hydrated to a maximum extent?

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  11. The alcohol with highest boiling point is

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  12. Which one of the following alcohols undergoes dehydration most easily?

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  13. The most suitable reagent for the conversion of R- CH(2) - OH rarr R...

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  14. In the reaction, underset("(Vapour)")(C(2)H(5)Oh)overset(Cu)underset(3...

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  15. A fruity smell is obtined by the reaction of ethanol with

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  16. In the manufacture of ethanol from sugar, the enzymes used are

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  17. In Lucas test of alcohols, appearance of cloudiness is due to the form...

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  18. The reactant (X) used in the following reaction is methyl magnesium br...

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  19. The order for the acidic strength of 1^(@),2^(@),3^(@) alcohols, H(2)O...

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  20. Which of the following are benzylic alcohols I C(6)H(5)-CH(2)-CH(2)O...

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