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The product formed during Hell-Volhard-Z...

The product formed during Hell-Volhard-Zelinsky reaction is

A

`underset(X) underset(|)(R-CH-)COOH`

B

`R-CH_(2)-COX`

C

`underset(X) underset(|)(R-C-)COOH`

D

`underset(X) underset(|)(R-CH-)CH_(2)-COOH`

Text Solution

Verified by Experts

The correct Answer is:
A

Carboxylic acids having an `alpha-` hydrogen are halogenated at the `alpha`- position on treatement with chlorine or bromine in the presence of small amunt of red phosphorus to give `alpha`-halocarboxylic acids. The reaction is know as Hell- Volhard-Zelinsky reaction.
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Carboxylic acids having atleast one alpha -hydrogen react with Cl_(2) or Br_(2) in the presence of phosphorus ( or a phosphorus halide) to give alpha -halo acids. This reaction is known as Hell-Volhard-Zelinsky reaction (HVZ reaction), R-CH_(2)COOHunderset(Delta)overset(P//Br_(2))toR-overset(Br)overset(|)"CH"-COOH The HVZ reaction is limited to the formation of alpha -chloro and a-bromo acids and it is sometimes awkward to carry out. The reagents ( X_(2) and P) are noxious and the reaction time is often long and the conditions of reaction are harsh. CH_(3)COOHoverset(Br_(2)//Red P)to(A)overset(NaCN)to(B)overset(HOH//H^(+))to(C ) The product (C) will be:

Carboxylic acids having atleast one alpha -hydrogen react with Cl_(2) or Br_(2) in the presence of phosphorus ( or a phosphorus halide) to give alpha -halo acids. This reaction is known as Hell-Volhard-Zelinsky reaction (HVZ reaction), R-CH_(2)COOHunderset(Delta)overset(P//Br_(2))toR-overset(Br)overset(|)"CH"-COOH The HVZ reaction is limited to the formation of alpha -chloro and a-bromo acids and it is sometimes awkward to carry out. The reagents ( X_(2) and P) are noxious and the reaction time is often long and the conditions of reaction are harsh. CH_(3)CH_(2)COOHoverset(Red P +Br_(2))to(A)overset(alc. KOH)(B) . The product (B) is :

Which of the following undergoes Hell - Volhard - Zelinsky reaction ?

The product formed during the Kolbe's reaction is

MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-EXERCISE 2
  1. Bezaldehyde gives a positive test with

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  2. Acetaldehyde form a white crystalline precipitate mixing with a soluti...

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  3. The product formed during Hell-Volhard-Zelinsky reaction is

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  4. Which gives lactic acid on hydrolysis after reacting with HCN?

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  5. Benzaldehyde condense with acetaldehyde to produce

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  6. The correct order for the acidic strength of thhe following compounds ...

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  7. The reagent which does not give acid chloride on treating with a carbo...

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  8. Among the following , the most acicid is

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  9. Among the following, which compound is most acidic ?

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  10. Colouration of Br(2)//C Cl(4) will be discharged by

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  11. Which of the following product is fomred in the reaction CH(3)MgBr ...

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  12. Cinnamci acid is fomed when C(6)H(5)-CHO condenses with (CH(3)CO(2))O ...

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  13. Which of the reagents (s) is/are responsible for the conversion of tol...

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  14. The most suitable reagent A, for the reaction is/are

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  15. Name the product formed during the decarboxylation of malonic acid.

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  16. The refluxing of (CH3)2NCOCH3 with acid gives

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  17. Match the reactions given in Column I with the suitable reagents given...

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  18. Which of the following will be most readily dehydrate under acidic con...

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  19. At room temperature, formaldehyde changed to

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  20. Amide on heating with P(2)O(5) gives

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