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Copper can be extracted by hydrometallur...

Copper can be extracted by hydrometallurgy but not Zinc -explain.

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Copper can be extracted by hydrometallurgy but not zinc.
Explanation : `rarr E^(0)` value of `Zn^(+2)//Zn= -0.762V` is less than that of `E^(0)` value of `Cu^(+2)//Cu=0.337V.`
`rarr` from the above data zinc is a stronger reducing agent and can easily displace the `Cu^(+2)`ions present in the complex.
`underset(" Soluble complex")([Cu(CN)_(2)])+Znrarr([Zn(CN)_(2)])+underset("precipitate")(Cu)`
Zinc can be isolated by hydrometallurgy only when stronger reducing agents than zinc are present.
So zinc cannot be extracted by hydrometallurgy.
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Knowledge Check

  • Silver can be precipitated in hydrometallurgy by using aluminium. This is because

    A
    silver is more electropositive metal
    B
    aluminium is more electronegative metal
    C
    silver is a good oxidising agent
    D
    aluminum is a good reducing agent
  • Silver can be precipitated in hydrometallurgy by using aluminiuin. This is because

    A
    silver is more electropositive metal
    B
    aluminium is more electronegative metal
    C
    silver is a good oxidising agent
    D
    aluminium is a good reducing agent
  • Hydrometallurgy is useful in the extraction of

    A
    Sn
    B
    Al
    C
    Cu
    D
    Mg
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