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Why boron does not exist as B^(2+) ion i...

Why boron does not exist as `B^(2+)` ion in solution or in compound ?

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Boron has three electrons in its valence shell `(3s^(2) 3p^(1))`. The sum of the first three ionisation enthalpies for boron is very high. Thus, the total energy required to produce `B^(3+)`ion is much more than would be compensated by the hydration enthlpy, and hence `B^(3+)` ion does not exist. The sum of the first three ionistion enthalpies is also not overcome by the lattice enthalpy of the compound in the solid state, and hence `B^(3+)` ion does not exist in the compound.
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Knowledge Check

  • Which of the ions does not exist ?

    A
    `PCl_(6)^(-)`
    B
    `NH_(4)^(+)`
    C
    `PBr_(6)^(-)`
    D
    `I_(3)^(-)`
  • Boron does not form B^(3+) ion, due to.

    A
    Energy required to form `B^(3+)` ion is very high which will not be compensated by lattice enthalpies or hydration enthalpies of such ion.
    B
    Boron is a non-metal
    C
    Boron is a metalloid
    D
    None of the above
  • Boron does not form B^(3+) ion, because:

    A
    Energy required to form `B^(3+)` ion is very high which will not be compensated by lattice enthalpies of hydration enthalpies of such ion.
    B
    Boron is a non-metal.
    C
    Boron is a metalloid.
    D
    None of the above.
  • CENGAGE CHEMISTRY-P-BLOCK GROUP 13 - BORON FAMILY-Ex 6.1 (Subjective)
    1. Why boron does not exist as B^(2+) ion in solution or in compound ?

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    2. The +1 oxidation state is more stable than +3 oxidation state for thal...

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    3. Aluminium chloride exists as dimer. Give reason.

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    4. Why boron halides do not exists as a dimer. While AlCl(3) exists as Al...

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    5. Give reaction for the following : (a) In (III) is more stable than i...

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    6. Why boron and aluminium tend to for, covalent compounds ?

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    7. Molten aluminium bromide is a poor conductor of electricity. Give reas...

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    8. Why B-X bond distance in BX(3) is shorter than theoretically expected ...

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    9. Boric acid can be titrated against sodium hydroxide using phenolphthal...

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    10. Which one is more soluble in diethyl ether : anhydrous AlCl(3) or hydr...

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    11. How is boron obtained from borax ? Give the chemical reactions involve...

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    12. Unlike ordinary fire, thermite reaction cannot be stopped by pouring w...

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    13. (a) Explain why BF(3) exists whereas BH(3) does not. (b) Compare the...

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    14. State with equations what happens when borax is heated on a platinum w...

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    15. What is inorganic benzene ? Why is it so called ? How will you get it ...

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    16. AlF(3) is insoluble in anhydrous HF but dissolves on addition of NaF. ...

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    17. What do you understand by : (a) Ammonal (b) Bentonite ( c) Rubie...

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