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Why boron does not exist as B^(2+) ion i...

Why boron does not exist as `B^(2+)` ion in solution or in compound ?

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Boron has three electrons in its valence shell `(3s^(2) 3p^(1))`. The sum of the first three ionisation enthalpies for boron is very high. Thus, the total energy required to produce `B^(3+)`ion is much more than would be compensated by the hydration enthlpy, and hence `B^(3+)` ion does not exist. The sum of the first three ionistion enthalpies is also not overcome by the lattice enthalpy of the compound in the solid state, and hence `B^(3+)` ion does not exist in the compound.
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Knowledge Check

  • Which of the ions does not exist ?

    A
    `PCl_(6)^(-)`
    B
    `NH_(4)^(+)`
    C
    `PBr_(6)^(-)`
    D
    `I_(3)^(-)`
  • Boron does not form B^(3+) ion, due to.

    A
    Energy required to form `B^(3+)` ion is very high which will not be compensated by lattice enthalpies or hydration enthalpies of such ion.
    B
    Boron is a non-metal
    C
    Boron is a metalloid
    D
    None of the above
  • Boron does not form B^(3+) ion, because:

    A
    Energy required to form `B^(3+)` ion is very high which will not be compensated by lattice enthalpies of hydration enthalpies of such ion.
    B
    Boron is a non-metal.
    C
    Boron is a metalloid.
    D
    None of the above.
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