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Assertion (A) : Pb^(+4) compounds are s...

Assertion (A) :` Pb^(+4)` compounds are stronger oxidiising agents than ` Sn^(4+)` compounds .
Reason (R): The higher oxidation states for group `14` elements are more stable for the heavier members of the group due to inert pair effect .

A

If bothe (A) and ( R) are correct and (R) is correct eplanation of (A)

B

If bothe (A) and ( R) are correct and (R) is correct eplanation of (A)

C

If (A) is correct , buyt (R) is incrorect .

D

If (A) is incrorect byt ( R) is correct .

Text Solution

Verified by Experts

The correct Answer is:
C

Aswsertion (A) is true , reason (R) is false .
Down the group , the inert pair effect incerases , therefore , the higher oxidation state becomes less stabnle , and the lower oxidation state becomes more stable down the proup .`Pb^(4+)` has a higher tendency to pass into `Pb^(2+)` and is , therefore , a good oxidisng agent compared to `Sn^(4+)`.
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(a) Statement I is true, Satement II is true, Statement II is the correct explanaition of Statement I. (b) Statement I is true, Satement II is true, Statement II is not the correct explanaiton of Statement I. (c ) Statement I is true, Statement II is false (d) Statement I is false : Statement II is true 2. Statement I : Pb^(4+) compounds are stronger oxidising agents than Sn^(2+) compounds . Statement II : The lower oxidation states for the group 14 elements are more stable for the heavier members of the group due to 'inert pair effect'

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Knowledge Check

  • Assertion (A) : Pb^(+4) compounds are stronger oxidiising agents than Sn^(3+) compounds . Reason (R): The higher oxition states for grouup 14 eelments are more stable for the heavier members of the frop due to inert pair effect .

    A
    If both (A) and (R) are correct and (R) is correct explanation of (A)
    B
    If both (A) and (R) are correct and (R) is not correct explanation of (A)
    C
    If (A) is correct , but (R) is incorrect
    D
    If (A) is incorrect but (R) is correct .
  • Statement 1: Pb^(4+) compounds are stronger oxidizing agents than Sn^(4+) compounds. statement 2: The higher oxidation states for the group 14 elements are more stable for the heavier members of the group due to 'inert pair effect'.

    A
    Statement 1 is true, statement 2 is true, statement 2 si a correct explanation for statement 11
    B
    Statement 1 is true, statement 2 is true, statement 2 is not a correct explanation for statement 11
    C
    Statement 1 is true, statement 2 is false
    D
    Statement 1 is false, statement 2 is true
  • Statement-1. Pb^(4+) compounds are stronger oxidizing agent than Sn^(4+) compounds. Statement-2. The higher oxidation states for the group 14 elements are more stable for the heavier members of the group due to inert pair effect.

    A
    Statement-1 is True, Statement-2 is True , Statement-2 is a correct explanation for statement-1.
    B
    Statement-1 is True, Statement-2 is True , Statement-2 is not a correct explanation for statement-1.
    C
    Statement-1 is True, Statement-2 is False.
    D
    Statement-1 is False, Statement-2 is True.
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