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Bleaching powder and bleach solution are...

Bleaching powder and bleach solution are produced on a large scale and used in several hous-hold products. The effectiveness of bleach solution id often measured by iodometry.
`25 mL` of household bleach solution was mixed with `30 mL` of `0.50 M KI` and `10 mL` of `4N` acetic acid. In the titration of the liberated iodine, `48 mL` of `0.25 N Na_(2)S_(2)O_(3)` was used to reach the end point. The molarity of the household bleach solution is :

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The correct Answer is:
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Iodiometry is the estimation of reducing substantce by the use of standard `I_(2)`.
`I_(2)+S_(2)O_(3)^(2-)rarr S_(4)O_(6)^(2-)+2I^(Theta)`
`I_(2)=2I^(Theta)=2S_(2)O_(3)^(2-)`
`Ew(S_(2)O_(3)^(2-))= (Mw)/('n'"factor") ( .:' n "factor" = (2)/(2)=1)`
`Ew(I_(2))=(Mw)/('n' "factor") ( :' n "factor" =2)`
Iodometry is the estimation of oxidising substance involving the liberation of `I_(2)` and subsequent volumetric estimation of `I_(2)`.
`2Cu^(2+) + 4I^(Theta)rarr CuI_(2)+I_(2)`
`CuI_(2)rarr Cu_(2)I_(2)+I_(2)`
`(Cu^(2+)` changes to `Cu^(Theta)`, so `Ew(Cu^(2+))=(Mw)/(1))`
`2S_(2)O_(3)^(2-)+I_(2)rarr 2I^(Theta)+S_(4)O_(6)^(2-)`
`:.` mEq of `S_(2)O_(3)^(2-) = 0.25 Nxx48(mL)=12`
mEq of `S_(2)O_(3)^(2-)-=mEq of I_(2)-=mEq of CI_(2)=12`
'n' factor for `CI_(2) = 2`
`:.` m mol of `CI_(2)=(12)/(2)=6=m` mol of `CaCOI_(2)`
`underset(('n' "factor"=2))underset("Containing" CI_(2))("Bleach") +KI+CH_(3)COOH rarr underset(('n' "factor"=2)) (I_(2))-= underset(('n' "factor"=1))(S_(2)O_(3)^(2-))`
So, molarity of `CaOCI_(2)=(m "moles")/(mL)=(6)/(25)=0.24`
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विरंजक चूर्ण और विरंजक विलयन का बड़ी मात्रा में उत्पाद किया जाता है। इसका प्रयोग कई घरेलू उत्पादों में होता है। विरंजक विलयन की कार्यक्षमता अक्सर आयोडोमिट्री में मापी जाती है।
घरेलू विरंजक विलयन के 25 मिली को 0.50 M KI के 30 मिली और 4N ऐसीटिक अम्ल के 10 मिली के साथ मिलाया गया। निस्तारित आयोडीन के अंतीय अनुमापन के लिए `0.25N Na_(2)S_(2)O_(3)` के 48 मिली लगे। घरेलू विरंजक विलयन की मोलरता क्या है?

लेखांश - :
विरंजक चूर्ण तथा विरंजक विलयन का उत्पादन बड़े पैमाने पर किया जाता है तथा यह बहुत-से गृहोपयोगी वस्तुओं में प्रयोग होते हैं । विरंजक विलयन की प्रभाव क्षमता का मापन आयोडोमिट्री (iodometry) द्वारा किया जाता है ।
विरंजक चूर्ण का एक घटक एक ऑक्सोअम्ल का लवण होता है इस ऑक्सोअम्ल का एनहाइड्राइड है

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