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Why is Cr^(2+) reducing and Mn^(3+) oxid...

Why is `Cr^(2+)` reducing and `Mn^(3+)` oxidising when both have `d^(4)` configuration ?

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`Cr(Z=24)=3d^54s^1`
`Cr^(2+)=3d^4`
`Cr^(2+)(3d^4)tounderset(t_(2g)^(3))(C)r^3+(3d^3)+e^(c-)`
`Cr^(2+)` undergoes oxidation and hence is reducing as its configuration changes from `d^4` to `d^3`, the latter having a half filled `t_(2g)^3` level.
On the other hand, the reduction of `Mn^(3+)` to `Mn^(2+)` results in the half-filled `(3d^5)` configuration which has extra stability,
And thus is oxidising.
`Mn(Z=25)=3d^54s^2,Mn^(2+)=3d^5,Mn^(3+)=3d^4`
`Mn^(3+)(3d^4)+e^(c-)toMn^(2+)(3d^5)`
[Undergo reduction and thus is oxidising]
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Assertion : Cr^(2+) is reducing and Mn^(3+) is oxidising. Reason : Cr^(2+) and Mn^(3+) have d^4 configuration.

The ion Cr^(2+) is redusing agent while that of Mn^(3+) is an oxidising agent though both have 3d^(4) configuration. This is because

Assertion :- Cr^(+2) is a reducing agent and Mn^(+3) is oxidising agent. Reason :- Mn^(+3) has d^(5) configuration.

How would you account for the following: (i) Cr^(2+) is reducing in nature while with the same d-orbital configuration (d^(4)) Mn^(3+) is an oxidising agent (ii) In a transition series of metals, the metal which exhibits the greatest number of oxidation state occurs in the middle of the series.

How would you account for the following? (i) Cr^(2+) is reducing in nature while with the same d-orbital configuration (d^14) Mn^(3+) is an oxidising agent. (ii) In a transition series of metals, the metal which exhibits the greatest number of oxidation states occurs in the middle of the series. (iii) Metal-metal bonding is more frequent for the 4d and the 5d series of transition metals than for the 3d series.

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