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Using the curved-arrow notation, show th...

Using the curved-arrow notation, show the formation of reactive intermediates when the following convalent bonds undergo heterolytic cleavage :
(a) `CH_3 - S - CH_3`
(b) `CH_3 - CN`
( c) `CH_3 - Cu` .

Text Solution

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.
(Cu is more electropositive than C)
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Knowledge Check

  • In CH_(3)CH_(2)OH the bond that undergoes heterolytic cleavage most readily is:

    A
    `C-C`
    B
    `C-O`
    C
    `C-H`
    D
    `O-H`

  • In CH_(3)CH_(2)OH, the bond that undergoes heterolytic cleavage most readily is

    A
    `C-C`
    B
    `C-O`
    C
    `O-H`
    D
    `C-H`

  • In CH_(3)CH_(2)OH , the bond that undergoes heterolytic cleavage most readily is

    A
    C-C
    B
    C-O
    C
    C-H
    D
    O-H

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    Using curved arrow notation show the formation of reaction intermediates when the following covalent bonds undergo heterolysis. (i) H_(3)C-CH_(2)-Cl" " (ii) H_(3)C-C equiv N" " (iii) CH_(3)ONa

    Using curved-arrow notation, show the formation of reactive intermediates when convalent bonds in the following substance undergo heterolytic (polar) cleavage. (i) CH_(3)-SCH_(3) , (ii) CH_(3)-CN (iv) CH_(3)-Cu , (iv) Ag-I (v) H_(3)N^(+)-BF_(3) , (vi) Cu(-OH_(2))_(4)^(2+) Stratergy: Both bonding electrons remain with the more electronegative atom. If the bonding atom have same electronegetivities,, then the bonding electrons are taken away by the larger atom as it can sustain the negative charge more effectively.

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    In CH_(3)CH_(2)OH , the bond that undergoes heterolytic cleavage most readily is

    In CH_(3)CH_(2)OH , the bond that undergoes heterolytic cleavage most readily is:

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