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Calculate standard heat of formation of `CS_(2)`. Given that standard heat of combustion of `C,S` and `CS_(2)` are `-393.3,-293.72` and `-1108.76kJ mol^(-1)`.

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To calculate the standard heat of formation of carbon disulfide (CS₂), we can use the standard heats of combustion of carbon (C), sulfur (S), and carbon disulfide (CS₂) that are provided. The standard heat of formation (ΔH_f°) can be derived from the heats of combustion using Hess's law. ### Step-by-Step Solution: 1. **Write the combustion reactions**: - For carbon: \[ C(s) + O_2(g) \rightarrow CO_2(g) \quad \Delta H = -393.3 \, \text{kJ/mol} ...
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The combustion of butane (C_(4)H_(10)) is exothermic by 2878.7 kJ "mol"^(-1) .Calculate the standard enthalpy of formation of butane given that the standard enthalpies of formation of CO_(2)(g) and H_(2)O(l) are -393.5 kJ "mol"^(-1) and -285.8 kJ "mol"^(-1) respectively.

Calculate the standard heat of formation of carbon disulphide (l). Given that the standard heats of combustion of carbon (s), sulphur (s) and carbon disulphide (l) are -393.3, -293.72 and -1108.76 kJ mol^(-1) respectively.

Knowledge Check

  • The heat of combustion of C, S and CS_(2) are -393.3kJ, -293.7kJ and -1108.76kJ. What will be the heat of formation of CS_(2) ?

    A
    `-128.02kJ`
    B
    `+970kJ`
    C
    `+1108.7kJ`
    D
    `+12kJ`
  • The standard heat of formation of carbon disulphide (l) given that standard heat of combustion of carbon (s), sulphur (s) and carbon disulphide (l) are -393.3, -293.72 and -1108.76 KJ mol^(-1) respectively is

    A
    `-12.502 KJ. Mol^(-1)`
    B
    `+128.02 KJ.mol^(-1)`
    C
    `-128.02 KJ.mol^(-1)`
    D
    `+12.802 KJ.mol^(-1)`
  • Calculate the standard heat of formation of carbon disulphide (l), given that the standard heat of combustion of carbon (s), sulphur (s) and carbon disulphide (l) are -393.3, -293.72 and -1108.76 kJ mol^(-1) respectively

    A
    `-128.02 kJ mol^(-1)`
    B
    `+12.802 kJ mol^(-1)`
    C
    `+128.02 kJ mol^(-1)`
    D
    `-12.802 kJ mol^(-1)`
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    Calculate the standard heat of formation of carbon disulphide (l) . Given that the standard heats of combusion of carbon (s) , sulphur (s) and acrbon disulphide (l) are -390, 290.0 , and -1100.0kJ mol^(-1) . Respectively.

    Calculate standard enthalpies of formation of carbon-di -sulphide (l) . Given the standard enthylpy of combustion of carbon (s), sulphur (s) & carbon-di-sulphide (l) are :- 393.3, -293.72 and -1108.76 kJ mol^(-1) respectively.

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