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The frequency of 1st line Balmer series ...

The frequency of 1st line Balmer series in `H_(2)` atom is `v_(0)`. The frequency of line emitted by single ionised He atom is

A

`2v_(0)`

B

`4v_(0)`

C

`v_(0)//2`

D

`v_(0)//4`

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The correct Answer is:
To solve the problem, we need to determine the frequency of the first line of the Balmer series for a singly ionized helium atom (He⁺) based on the frequency of the first line of the Balmer series in a hydrogen atom (H₂) given as \( v_0 \). ### Step-by-Step Solution: 1. **Understanding the Balmer Series**: The Balmer series corresponds to transitions of electrons in hydrogen (and hydrogen-like atoms) from higher energy levels to the second energy level (n=2). The first line of the Balmer series corresponds to the transition from n=3 to n=2. 2. **Frequency Relation in Hydrogen**: The frequency of the emitted photon during this transition can be expressed using the Rydberg formula: \[ v = R_H \left( \frac{1}{n_2^2} - \frac{1}{n_1^2} \right) \] where \( R_H \) is the Rydberg constant for hydrogen, \( n_1 = 2 \), and \( n_2 = 3 \). 3. **Ionized Helium Atom (He⁺)**: The singly ionized helium atom (He⁺) is a hydrogen-like atom with \( Z = 2 \) (where Z is the atomic number). The frequency of the emitted photon for He⁺ can be similarly expressed: \[ v_{He^+} = R_{He} \left( \frac{1}{n_2^2} - \frac{1}{n_1^2} \right) \] where \( R_{He} = Z^2 R_H = 2^2 R_H = 4 R_H \). 4. **Calculating the Frequency for He⁺**: For the transition from n=3 to n=2 in He⁺, we have: \[ v_{He^+} = 4 R_H \left( \frac{1}{2^2} - \frac{1}{3^2} \right) \] This can be simplified to: \[ v_{He^+} = 4 R_H \left( \frac{1}{4} - \frac{1}{9} \right) \] To combine the fractions: \[ \frac{1}{4} - \frac{1}{9} = \frac{9 - 4}{36} = \frac{5}{36} \] Thus, \[ v_{He^+} = 4 R_H \cdot \frac{5}{36} = \frac{20 R_H}{36} = \frac{5 R_H}{9} \] 5. **Relating to \( v_0 \)**: Since we know that the frequency of the first line of the Balmer series in hydrogen is given as \( v_0 \): \[ v_0 = R_H \left( \frac{1}{4} - \frac{1}{9} \right) = R_H \cdot \frac{5}{36} \] Therefore, we can express \( R_H \) in terms of \( v_0 \): \[ R_H = \frac{36 v_0}{5} \] 6. **Substituting \( R_H \) back**: Now substituting this back into the frequency for He⁺: \[ v_{He^+} = \frac{5}{9} \cdot \frac{36 v_0}{5} = \frac{36 v_0}{9} = 4 v_0 \] ### Final Answer: The frequency of the line emitted by the singly ionized helium atom is \( 4 v_0 \).

To solve the problem, we need to determine the frequency of the first line of the Balmer series for a singly ionized helium atom (He⁺) based on the frequency of the first line of the Balmer series in a hydrogen atom (H₂) given as \( v_0 \). ### Step-by-Step Solution: 1. **Understanding the Balmer Series**: The Balmer series corresponds to transitions of electrons in hydrogen (and hydrogen-like atoms) from higher energy levels to the second energy level (n=2). The first line of the Balmer series corresponds to the transition from n=3 to n=2. 2. **Frequency Relation in Hydrogen**: ...
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