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PCl5 in solid state exists as PCl4^+ and...

`PCl_5` in solid state exists as `PCl_4^+` and `PCl_6^-`. Also in some solvents it undergoes dissoctation as ` 2PCl_5 hArr PCl_2^+ +PCl_6^-`.
The geometry and hybridisation of `PCl_5` is :

A

trigonal bipyramid , `sp^3 d `

B

tetrahedral , `sp^3`

C

octahderal , `sp^3 d^2`

D

octahedral , `sp^3 d^2`

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The correct Answer is:
A
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PCl_5 in solid state exists as PCl_4^+ and PCl_6^- Also in some solvents it undergoes dissoctation as 2PCl_5 hArr PCl_2^+ +PCl_6^- . The geometry and hybridisation of PCl_4^+ is :

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PCl_5 in solid state exists as PCl_4^+ and PCl_6^- Also in some solvents it undergoes dissoctation as 2PCl_5 hArr PCl_2^+ +PCl_6^- . The oxidation number of P in PCl_5 .PCl_4^+ and PCl_6^- are respectively :

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P BAHADUR-CHEMICAL BONDING-Exercise 6
  1. PCl5 in solid state exists as PCl4^+ and PCl6^-. Also in some solvents...

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  2. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  3. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  4. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  5. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  6. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  7. Lewis concept of covalency of an element involved octet rule .Later o...

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  8. Lewis concept of covalency of an element involved octet rule .Later o...

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  9. Lewis concept of covalency of an element involved octet rule .Later o...

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  10. Lewis concept of covalency of an element involved octet rule .Later o...

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  11. Lewis concept of covalency of an element involved octet rule .Later o...

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  12. Lewis concept of covalency of an element involved octet rule .Later o...

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  13. Lewis concept of covalency of an element involved octet rule .Later o...

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  14. Lewis concept of covalency of an element involved octet rule .Later o...

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  15. To explain the abnormality in some molecules , the conecpt of H-bondin...

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  16. To explain the abnormality in some molecules , the conecpt of H-bondin...

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  17. To explain the abnormality in some molecules , the conecpt of H-bondin...

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  18. To explain the abnormality in some molecules , the conecpt of H-bondin...

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  19. To explain the abnormality in some molecules , the conecpt of H-bondin...

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