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The number of mole of KMnO(4) that will ...

The number of mole of `KMnO_(4)` that will be needed to react completely with one mole of ferrous oxalate in acidic solution is:

A

(a)`0.6` mole

B

(b)`0.4` mole

C

(c )`7.5` mole

D

(d)`0.2` mole

Text Solution

Verified by Experts

The correct Answer is:
a

In ferrous oxalate ferrous and oxalate ions are oxidized.
`Fe^(2+) rarr Fe^(3+)+e^(-)`
`C_(2)O_(4)^(2-) rarr 2CO_(2)+2e^(-)`
`MnO_(4)^(2-) rarr Mn^(2+)`
Thus eqn. will be `3MnO_(4)^(-)+5FeC_(2)O_(4) rarr`
`implies` 1 mole of ferrous oxalate requires `3//5` moles of `KMnO_(4)`, i.e., 0.6 mole.
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