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The correct increasing order of basic st...

The correct increasing order of basic strength of the labeled `N` is:

A

`I lt II lt III lt IV`

B

`I lt II lt IV lt III`

C

`I lt III lt IV lt II`

D

`IV lt III lt II lt I`

Text Solution

Verified by Experts

The correct Answer is:
B

`III` is most basic nitrogen because protonation here produces resonance stabilised conjugate acid.

`I` is least basic as lone pair of nitrogen is delocalized over two carbonyl groups. `II` is less basic than `IV` because lone pair of nitrogen `II` is more delocalized, less available for donation.
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A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Acid And Basic Strength
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  2. The correct increasing order of basic strength of the labeled N is:

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  3. Among the following compounds, the strongest acid is :

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  4. The correct order of nucleophilicity among the following is: (I) CH(...

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  5. Find the order of basic strength, (if R=Me). (I) R(4)OH^(-), (II) R(3...

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  6. Which is most basic in the following compounds?

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  7. Select the basic order of following molecules.

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  8. Out of the following compunds, which will have a zero diopole moment?

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  9. Arrange the following in increasing order of basic strength

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  10. Choose the strongest base among the following:

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  11. Which of the following has lowest melting point?

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  12. Select the basic strength order of following molecules

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  13. What is formed in the above reaction?

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  14. Consider thiol anion (RS^(Theta)) and alkoxy anion (RO^(Theta)). Which...

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  15. The correct basic strength order of the following anions is:

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  16. Which of the following has the most acidic hydrogen ?

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  17. Which of the following cannot be a base?

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  18. Arrange above phenol in increasing order of pK(a) value:

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  19. Arrange the following compounds in decreasing order of their acidic st...

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  20. Which compound would be least soluble in water?

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