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Assertion: Transitio metals show variabl...

Assertion: Transitio metals show variable valence.
Reason : Due to a large energy difference bteween the `ns^(2)` and `(n - 1)d` electrons.

A

If both assetion and reason are true and the reason is the correct explanation of the assertion.

B

If both assertion and reason are ture but reason is not the correct explanation of the assertion.

C

If assertion is true but reason is false.

D

If assertion is false but reason is true.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Transition metals show variable valence." This is true because transition metals can lose different numbers of electrons from their d and s orbitals, leading to various oxidation states. ### Step 2: Understand the Reason The reason given is "Due to a large energy difference between the ns² and (n-1)d electrons." This statement is incorrect. In transition metals, the energy difference between the ns and (n-1)d orbitals is actually small. This small energy gap allows for the easy removal of electrons from both the s and d orbitals, contributing to the variable valency. ### Step 3: Conclusion Since the assertion is true and the reason is false, we conclude that the correct relationship is that the assertion is true, but the reason is not valid. ### Final Answer The assertion is true, and the reason is false. Therefore, the correct answer is option C. ---

To solve the problem, we need to analyze the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Transition metals show variable valence." This is true because transition metals can lose different numbers of electrons from their d and s orbitals, leading to various oxidation states. ### Step 2: Understand the Reason The reason given is "Due to a large energy difference between the ns² and (n-1)d electrons." This statement is incorrect. In transition metals, the energy difference between the ns and (n-1)d orbitals is actually small. This small energy gap allows for the easy removal of electrons from both the s and d orbitals, contributing to the variable valency. ...
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The sum of ns and (n-1)d electrons in Tc are

Why penultimate shell (n-1)d e^(-) is reactive in transition element O energy of (n-1)d and ns is same O large energy difference between (n-1)d and ns O little energy difference between (n-1)d and ns O variable energy of (n-1)d

Knowledge Check

  • Assertion (A) : Transition metals have low melting points. Reason (R ) : The involvement of greater number of (n - 1)d and ns electrons in the interatomic metallic bonding.

    A
    Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of the Assertion (A).
    B
    Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation of the Assertion (A).
    C
    Assertion (A) is correct, but Reason (R) is incorrect statement.
    D
    Assertion (A) is incorrect, but Reason (R) is correct statement.
  • Assertion (A): Transition metals have low melting points. Reason (R): The involvement of greater number of (n-1)d and ns electrons in the interatomic metallic bonding.

    A
    Both A and Rare true and R is the correct explanation of A.
    B
    Both A and R are true but R is NOT the correct explanation of A.
    C
    A is true but R is false.
    D
    A is false and R is True
  • A metal M shows variable valencies 2 and 3. Calculate the ratio of oxygen atom present in their corresponding sulphates.

    A
    `1 : 3`
    B
    ` 3 : 1`
    C
    `3 : 4`
    D
    `3 : 2`
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    Assertion (A): Copper exhibits variable valency. Reason (R): Copper loses two electrons from its valence shell and it can also lose one more electron from the second last shell.

    A metal M shows variable valencies 2 and 3.Calculate the ratio of oxygen atoms present in their corresponding sulphates.

    Assertion: Mn atom loses ns electrons first during ionisation as compared to (n-1) d electrons Reason: The effective nuclear charge experienced by (n-1) d electrons is greater than that by ns electrons.

    Assertion: Manganese shows a number of oxidation states. Reason: The difference of energy between 3d and 4s subshells is large.