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The shape of [Cu(NH3)4]Cl2 is:...

The shape of `[Cu(NH_3)_4]Cl_2` is:

A

(a) Tetrahedral

B

(b) Octahedral

C

(c) Square planar

D

(d) Pyramidal

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The correct Answer is:
To determine the shape of the coordination compound \([Cu(NH_3)_4]Cl_2\), we can follow these steps: ### Step 1: Identify the central metal ion and its oxidation state - The complex \([Cu(NH_3)_4]Cl_2\) contains copper (Cu) as the central metal ion. - The ammonia (NH₃) ligands are neutral, and the two chloride ions (Cl⁻) contribute a -2 charge in total. - Therefore, to balance the -2 charge from the chlorides, copper must have a +2 oxidation state. ### Step 2: Determine the electronic configuration of the metal ion - Copper in the +2 oxidation state has the electronic configuration of \([Ar] 3d^9\). - This means that in the 3d subshell, there are 9 electrons. ### Step 3: Determine the coordination number - The complex has 4 ammonia ligands coordinated to the copper ion. - Therefore, the coordination number is 4. ### Step 4: Identify the hybridization - For a coordination number of 4, the possible hybridizations can be \(sp^3\) or \(dsp^2\). - In the case of copper(II) complexes, especially with a \(d^9\) configuration, the hybridization tends to be \(dsp^2\). ### Step 5: Determine the geometry - The \(dsp^2\) hybridization leads to a square planar geometry. - This is a common geometry for \(d^8\) and \(d^9\) metal complexes, where the ligands arrange themselves in a square planar fashion around the central metal ion. ### Conclusion - Therefore, the shape of the complex \([Cu(NH_3)_4]Cl_2\) is square planar. ---

To determine the shape of the coordination compound \([Cu(NH_3)_4]Cl_2\), we can follow these steps: ### Step 1: Identify the central metal ion and its oxidation state - The complex \([Cu(NH_3)_4]Cl_2\) contains copper (Cu) as the central metal ion. - The ammonia (NH₃) ligands are neutral, and the two chloride ions (Cl⁻) contribute a -2 charge in total. - Therefore, to balance the -2 charge from the chlorides, copper must have a +2 oxidation state. ### Step 2: Determine the electronic configuration of the metal ion ...
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A2Z-COORDINATION COMPOUNDS-Wemer Theory And Vbt
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  2. Which one of the following has lowest value of paramagnetic behaviour?

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  3. Velence bond theroy describes the bonding in complexs in terms of coor...

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  4. Nickel (Z=28) combines with a uninegative monodentate ligand X^(-) to ...

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  5. Which one of the following has a square planar geometry? (Co=27, Ni=...

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  6. The octahedral complex of a metal ion M^(3+) with four monodentate lig...

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  7. Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?

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  8. The magnetic moment (spin only) of [NiCl4]^(2+) is

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  9. Which of the following is a low spin complex?

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  10. Complexes with halide ligands are generally:

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  11. Among the following ions, which one has the highest paramagnetism?

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  12. Among [Ni(CO)4], [Ni(CN)4]^(2-), [NiCl4]^(2-) species, the hybridizati...

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  13. Which is correct in the case of [NiCl4]^(2-) complex?

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  14. The shape of [Cu(NH3)4]Cl2 is:

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  15. For which transition metal ions are low spin complexes possible:

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  16. An octahedral complex is formed when hybrid orbitals of the following ...

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  17. The primary valence of the metal ion in the coordination compound K2[N...

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  18. The number of unpaired electrons in the complex ion [CoF6]^(3-) is (At...

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  19. The compound which does not show paramagnetism is

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  20. When excess of ammonia is added to CuSO4 solution, the deep blue colou...

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