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The shape of [Cu(NH3)4]Cl2 is:...

The shape of `[Cu(NH_3)_4]Cl_2` is:

A

(a) Tetrahedral

B

(b) Octahedral

C

(c) Square planar

D

(d) Pyramidal

Text Solution

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The correct Answer is:
To determine the shape of the coordination compound \([Cu(NH_3)_4]Cl_2\), we can follow these steps: ### Step 1: Identify the central metal ion and its oxidation state - The complex \([Cu(NH_3)_4]Cl_2\) contains copper (Cu) as the central metal ion. - The ammonia (NH₃) ligands are neutral, and the two chloride ions (Cl⁻) contribute a -2 charge in total. - Therefore, to balance the -2 charge from the chlorides, copper must have a +2 oxidation state. ### Step 2: Determine the electronic configuration of the metal ion - Copper in the +2 oxidation state has the electronic configuration of \([Ar] 3d^9\). - This means that in the 3d subshell, there are 9 electrons. ### Step 3: Determine the coordination number - The complex has 4 ammonia ligands coordinated to the copper ion. - Therefore, the coordination number is 4. ### Step 4: Identify the hybridization - For a coordination number of 4, the possible hybridizations can be \(sp^3\) or \(dsp^2\). - In the case of copper(II) complexes, especially with a \(d^9\) configuration, the hybridization tends to be \(dsp^2\). ### Step 5: Determine the geometry - The \(dsp^2\) hybridization leads to a square planar geometry. - This is a common geometry for \(d^8\) and \(d^9\) metal complexes, where the ligands arrange themselves in a square planar fashion around the central metal ion. ### Conclusion - Therefore, the shape of the complex \([Cu(NH_3)_4]Cl_2\) is square planar. ---

To determine the shape of the coordination compound \([Cu(NH_3)_4]Cl_2\), we can follow these steps: ### Step 1: Identify the central metal ion and its oxidation state - The complex \([Cu(NH_3)_4]Cl_2\) contains copper (Cu) as the central metal ion. - The ammonia (NH₃) ligands are neutral, and the two chloride ions (Cl⁻) contribute a -2 charge in total. - Therefore, to balance the -2 charge from the chlorides, copper must have a +2 oxidation state. ### Step 2: Determine the electronic configuration of the metal ion ...
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Knowledge Check

  • The shape of [Cu(NH_3)_4]SO_4 is :-

    A
    Square planar
    B
    Pyramidal
    C
    Octahedral
    D
    Tetrahedral
  • The shape of [Cu(NH_3)_4]SO_4 is :-

    A
    Square planar
    B
    Pyramidal
    C
    Octahedral
    D
    Tetrahedral
  • The shape of [Cu(NH_3)_4]^(2+) is square planar, Cu^(2+) in this complex is

    A
    `sp^3` hybridised
    B
    `dsp^2` hybridised
    C
    `sp^3d` hybridised
    D
    `sp^3d^2` hybridised
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