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Which of the following is not optically ...

Which of the following is not optically active?

A

(a) `[Co(en)_3]^(3+)`

B

(b) `[Cr(o x)_3]^(3-)`

C

(c) `cis-[CoCl_2(en)_2]^(+)`

D

(d) `trans-[CoCl_2(en)_2]^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds is not optically active, we need to analyze the options based on their molecular geometry and symmetry. ### Step-by-Step Solution: 1. **Understand Optical Activity**: Optical activity refers to the ability of a compound to rotate plane-polarized light. A compound is optically active if it lacks an internal plane of symmetry and has a chiral center. 2. **Identify the Types of Ligands**: - The question mentions different ligands (like MAA3 and oxalato) which are bidentate ligands. Bidentate ligands can form chelate complexes with metal ions. 3. **Analyze the Given Options**: - **Option A (MAA3)**: This compound is symmetrical and exists in only one form, which is optically active. - **Option B (Oxalato)**: Similar to option A, oxalato is also a symmetrical bidentate ligand and is optically active. - **Option C and D**: These options represent compounds that can exist in both cis and trans forms. 4. **Cis and Trans Isomerism**: - In coordination compounds, cis and trans isomers can exhibit different optical activities. - The **cis form** is typically optically active because it lacks symmetry. - The **trans form**, however, is usually optically inactive due to its symmetrical arrangement. 5. **Conclusion**: - Since options A and B are optically active, and option C has both cis (optically active) and trans (optically inactive) forms, the answer to the question "Which of the following is not optically active?" is the **trans form** of the compound in option C or D. ### Final Answer: The compound that is not optically active is the **trans form** of the coordination compound.

To determine which of the given compounds is not optically active, we need to analyze the options based on their molecular geometry and symmetry. ### Step-by-Step Solution: 1. **Understand Optical Activity**: Optical activity refers to the ability of a compound to rotate plane-polarized light. A compound is optically active if it lacks an internal plane of symmetry and has a chiral center. 2. **Identify the Types of Ligands**: ...
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A2Z-COORDINATION COMPOUNDS-Optical Isomerism
  1. Which of the following is not optically active?

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  2. Which of the following types of octahedral complexes does not show opt...

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  3. Type of isomerism which is shown by [PtCl2Br2]^(2-) is also observed i...

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  4. Which of the following statements is not true about the complex ion [P...

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  5. Tris (ethylenediamine) cobalt (III) cation, [Co(en)3]^(3+), can have

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  6. Which one of the following complexes exhibit chirality?

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  7. Which of the following complex will show optical activity?

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  8. Which of the following is considered to be an anticancer species ?

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  9. [Co(en)3]^(3+) ion is expected to show

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  10. In which case racemic mixture is obtained on mixing its mirror images ...

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  11. The complex that exists as a pair of enantiomers is

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  12. Which of the following complexes exhibit optical isomerism?

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  13. The complex shown below can exhibit

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  14. Which of the following has the largest number of isomers? .

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  15. Which of the following will show optical isomerism? .

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  16. Which of the folloiwng complexes in not expected to exhibit optical is...

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  17. Which of the following has an optical isomer? (en=ethylenediamine) ?

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  18. Which of the following has an optical isomer?

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  19. The number of isomeric forms in which [Co(NH3)4Cl2]^(+) ion can occur ...

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  20. The phenomenon of optical activity will be shown by:

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