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Which of the following is not optically ...

Which of the following is not optically active?

A

(a) `[Co(en)_3]^(3+)`

B

(b) `[Cr(o x)_3]^(3-)`

C

(c) `cis-[CoCl_2(en)_2]^(+)`

D

(d) `trans-[CoCl_2(en)_2]^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds is not optically active, we need to analyze the options based on their molecular geometry and symmetry. ### Step-by-Step Solution: 1. **Understand Optical Activity**: Optical activity refers to the ability of a compound to rotate plane-polarized light. A compound is optically active if it lacks an internal plane of symmetry and has a chiral center. 2. **Identify the Types of Ligands**: - The question mentions different ligands (like MAA3 and oxalato) which are bidentate ligands. Bidentate ligands can form chelate complexes with metal ions. 3. **Analyze the Given Options**: - **Option A (MAA3)**: This compound is symmetrical and exists in only one form, which is optically active. - **Option B (Oxalato)**: Similar to option A, oxalato is also a symmetrical bidentate ligand and is optically active. - **Option C and D**: These options represent compounds that can exist in both cis and trans forms. 4. **Cis and Trans Isomerism**: - In coordination compounds, cis and trans isomers can exhibit different optical activities. - The **cis form** is typically optically active because it lacks symmetry. - The **trans form**, however, is usually optically inactive due to its symmetrical arrangement. 5. **Conclusion**: - Since options A and B are optically active, and option C has both cis (optically active) and trans (optically inactive) forms, the answer to the question "Which of the following is not optically active?" is the **trans form** of the compound in option C or D. ### Final Answer: The compound that is not optically active is the **trans form** of the coordination compound.

To determine which of the given compounds is not optically active, we need to analyze the options based on their molecular geometry and symmetry. ### Step-by-Step Solution: 1. **Understand Optical Activity**: Optical activity refers to the ability of a compound to rotate plane-polarized light. A compound is optically active if it lacks an internal plane of symmetry and has a chiral center. 2. **Identify the Types of Ligands**: ...
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