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CHEMISTRY
Hydrolysis of ethyl cyanide gives :...

Hydrolysis of ethyl cyanide gives `:`

A

Formic acid

B

Acetic acid

C

Propionic acid

D

Acetaldehyde

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The correct Answer is:
To solve the question regarding the hydrolysis of ethyl cyanide, we will follow these steps: ### Step 1: Identify Ethyl Cyanide Ethyl cyanide, also known as ethyl carbamate, has the chemical formula C2H5C≡N. It contains a cyano group (C≡N) attached to an ethyl group (C2H5). ### Step 2: Perform Acid Hydrolysis When ethyl cyanide undergoes hydrolysis, it reacts with water in the presence of an acid (H+). The acid will protonate the cyano group, making it more susceptible to nucleophilic attack by water. ### Step 3: Formation of Intermediate The first step of hydrolysis involves the attack of water on the cyano group: - The H+ from the acid attacks the nitrogen of the cyano group. - Water (H2O) donates a hydroxyl group (OH-) to the carbon of the cyano group. This results in the formation of an intermediate compound, which is an amide: \[ \text{C2H5C(OH)=N-H} \] ### Step 4: Further Hydrolysis The intermediate can undergo further hydrolysis: - Again, H+ from the acid will attack the nitrogen, and water will provide another hydroxyl group. - This leads to the formation of a compound with two hydroxyl groups on the same carbon. ### Step 5: Elimination of Water The presence of two hydroxyl groups on the same carbon is unstable, leading to the elimination of a water molecule. This results in the formation of an amide: \[ \text{C2H5C(=O)NH2} \] ### Step 6: Final Hydrolysis to Carboxylic Acid The amide can undergo further hydrolysis: - H+ from the acid attacks the carbon of the carbonyl group (C=O). - Water adds to the carbon, resulting in the formation of a carboxylic acid and ammonia. The final product is propionic acid (C2H5COOH) and ammonia (NH3). ### Conclusion The hydrolysis of ethyl cyanide results in the formation of propionic acid. ### Final Answer The correct answer is **C: Propionic acid**. ---

To solve the question regarding the hydrolysis of ethyl cyanide, we will follow these steps: ### Step 1: Identify Ethyl Cyanide Ethyl cyanide, also known as ethyl carbamate, has the chemical formula C2H5C≡N. It contains a cyano group (C≡N) attached to an ethyl group (C2H5). ### Step 2: Perform Acid Hydrolysis When ethyl cyanide undergoes hydrolysis, it reacts with water in the presence of an acid (H+). The acid will protonate the cyano group, making it more susceptible to nucleophilic attack by water. ...
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Knowledge Check

  • In presence of acid, hydrolysis of methyl cyanide gives

    A
    Ethanoic acid
    B
    Methylamine
    C
    Methyl alcohol
    D
    Formic acid
  • In the presence of acid, the hydrolysis of methyl cyanides gives

    A
    Methanoic acid
    B
    Ethanoic acid
    C
    Methylamine
    D
    Methyl alcohol
  • Hydrolysis of ethanoic anhydride gives

    A
    methanoic acid
    B
    propanoic acid
    C
    ethanoic acid
    D
    oxalic acid
  • MARVEL PUBLICATION-ALDEHYDES,KETONES AND CARBOXYLIC ACIDS-CARBOXYLIC ACIDS
    1. Alkyl cyanides on hydrolysis with mineral acids form :

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    2. When dry ice reacts with CH(3)MgBr the product is hydrolysed to give :

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    3. Hydrolysis of ethyl cyanide gives :

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    4. Which of the following ismore acidic in nature ?

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    5. Ethanoic acid is obtained from which of the following :

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    6. The strongest acid among the following :

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    7. A overset(KCN)(rarr)CH(3)CN underset(Boil ) overset("Alkali")(rarr) B,...

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    8. Consider the following sequence of reactions and identify the final pr...

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    9. What is the main reason for the fact that carboxylic acids can undergo...

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    10. With the increase in molecular weight,the acidic character of fatty ac...

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    11. The pKa values of stronger acids are :

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    12. 2-methyl propan nitrile on alkaline hydrolysis give :

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    13. Identify 'Product ' in the reaction : CH(3)COOH+NH(3) rarr "Intermed...

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    14. Which product distills over when a mixture of absolute alcohol and gla...

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    15. Which of the following carboxylic acid can be esterified most readily ...

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    16. The reaction between an alcohol and carboxylic acid is known as :

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    17. When formic acid is treated with ammonical silver nitrate it forms :

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    18. The formula (RCO)(2)O represents:

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    19. Which of the reactions are due to H^(+) ion of the -COOH group :

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    20. Which of the following indicate the presence of -OH group in -COOH gro...

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