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Isopropyl bromide when heated with alcoh...

Isopropyl bromide when heated with alcoholic KOH gives propene. The reaction is __________.

A

Substitution

B

Elimination

C

Addition

D

cyclisation

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The correct Answer is:
To determine the type of reaction that occurs when isopropyl bromide is heated with alcoholic KOH to produce propene, we can analyze the process step by step. ### Step 1: Identify the Reactants The reactant in this case is isopropyl bromide, which has the chemical formula \( \text{C}_3\text{H}_7\text{Br} \). It is an alkyl halide. **Hint:** Look for the structure of isopropyl bromide to understand what functional groups are present. ### Step 2: Understand the Role of Alcoholic KOH Alcoholic KOH is a strong base. In this reaction, it does not act as a nucleophile but rather as a base that facilitates the elimination of a hydrogen halide (HBr) from the alkyl halide. **Hint:** Recall the properties of strong bases and how they interact with alkyl halides. ### Step 3: Mechanism of the Reaction When isopropyl bromide is heated with alcoholic KOH, the hydroxide ion (\( \text{OH}^- \)) from KOH acts as a Bronsted base. It abstracts a hydrogen atom from the carbon adjacent to the carbon bonded to the bromine. **Hint:** Consider how the base interacts with the hydrogen atoms in the molecule. ### Step 4: Elimination of Bromine As the base removes a hydrogen atom, the bond between the carbon and the bromine atom becomes unstable. This leads to the elimination of bromine (Br) as bromide ion (\( \text{Br}^- \)). **Hint:** Think about the concept of elimination reactions where a small molecule (like HBr) is removed from the reactant. ### Step 5: Formation of the Product The result of this elimination is the formation of a double bond between the two carbon atoms, leading to the formation of propene (\( \text{C}_3\text{H}_6 \)). The overall reaction can be summarized as follows: \[ \text{C}_3\text{H}_7\text{Br} + \text{KOH} \rightarrow \text{C}_3\text{H}_6 + \text{HBr} + \text{KBr} \] **Hint:** Visualize the product formation and ensure you account for all atoms involved in the reaction. ### Conclusion The reaction of isopropyl bromide with alcoholic KOH to produce propene is classified as an **elimination reaction**. **Final Answer:** The reaction is an **elimination reaction**.
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Knowledge Check

  • Propyl bromide on reaction with alcoholic KOH gives-

    A
    Propane+Ethane
    B
    Propene
    C
    Butane
    D
    Acetylene
  • Ethyl bromide on treatment with alcoholic KOH gives

    A
    Ethylene
    B
    Ethanol
    C
    Acetic acid
    D
    Ethane
  • n-propyl bromide on treatment with alcoholic KOH produces

    A
    propane
    B
    propane
    C
    propyne
    D
    hypnotic
  • TARGET PUBLICATION-HALOGEN DERIVATIVES OF ALKANES AND ARENES-EVALUATION TEST
    1. Isopropyl bromide when heated with alcoholic KOH gives propene. The re...

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    2. In the following sequence of reactions, CH(3)CH(2)CH(2)Br overset("K...

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    3. In the following sequence of the reactions : CH(3)CH(2)CH(2)I overse...

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    4. In the reaction CH(3) C -= C^(-) - Na^(+) +(CH(3))(2) CH - Cl to ?...

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    5. Which one of the following is most reactive towards nucleophilic subst...

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    6. Isopropyl chloride undergoes hydrolysis by :

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    7. Which compound shows S(N)1 mechanism as well as optical isomerism ?

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    8. Aryl halides are less reactive towards nucleophilic substitution react...

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    9. Which chloroderivative of benzene among the following would undergo hy...

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    10. o-Toluic acid on reaction with Br(2) + Fe gives

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    11. The reaction of 4-bromobenzyl chloride with NaCN in ethanol leads to :

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    12. Identify 'C' in the following sequence : C(6)H(5)NH(2) underset(273 ...

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    13. The compound CH(3)-underset(Cl)underset(|)overset(CH(3))overset(|)C-CH...

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    14. Benzene reacts with CHCl(3) in the presence of arhydrous AlCl(3) to fo...

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    15. The intermediate during the addition of HI to propene in presence of p...

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    16. The organo bromo compound which shows complete stereochemical inversio...

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    17. An alkyl chloride produces a single alkene when it reacts with sodium ...

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    18. In the following reaction , C(6)H(5)CH(2)Broverset(1.Mg,Ether)underset...

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    19. An alkyl iodide (X) reacts with sodium in ether to form 4,5-diethyloct...

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    20. Which of the following is NOT a haloalkane ?

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