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The hydrogen electrode is prepared elect...

The hydrogen electrode is prepared electrochemically by depositing

A

Platinum on copper metal

B

Silver on platinum metal

C

Platinum on platinum metal

D

Palladium on palladium metal

Text Solution

Verified by Experts

The correct Answer is:
C

The normal hydrogen electrode or standard hydrogen electrode, which is used as a primary reference, consists of a piece of platinum foil, which is cpateed electrolytically with a very finely-devided platinum known as platinum black to give it a large surface area, suspended in a molar solution of hydrogen ions. Pure hydrogen gas at `1` bar pressure is continually bubbed into the solution to keep it saturated and to expose the soil alternately to gas and solution.
The platinum act as an electrical conductor and also facilitates the attainment of equilibrium between the gas and its ions in solution.
In practice a 1.18 `M` solution of hydrochloric acid is used so that the activity (i.e. the effectivity concentration) of the hydrogen ions in solution is exactly unity.
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Electrode Potential|Standard Hydrogen Electrode As Reference Electrode|Electrochemical Series|OMR|Summary

A hydrogen electrode is prepared by using a sample of HCl solution with pH=4 and H_(2) gas at 1 atm pressure. What is the electrode potential of the electrode?

Standard hydrogen electrode (SHE) is a

Assertion:A standard hydrogen electrode is also called reversible electrode. Reason : Standard hydrogen electrode can act both as anode as well as cathode in an electrochemical cell.

Knowledge Check

  • The hydrogen electrode potential depends on

    A
    Nature of metal used as anode
    B
    The `P^(H)` of the solution
    C
    Both nature of the metal used as anode and the `P^(H)` of the solution
    D
    Nature of the metal used as cathode and `P^(H)` of the soltion
  • A standard hydrogen electrode has zero electrode potential because :

    A
    hydrogen is easiest tio oxidise
    B
    this electrode potential is assumed to be zero
    C
    hydrogen atom has only one electron
    D
    hydrogen is the lightest element
  • A hydrogen electrode is prepared by using a sample of HCl solution with pH=4 and H_(2) gas at 1 atm pressure. What is the electrode potential of the electrode?

    A
    0.814 V
    B
    0.236 V
    C
    `-0.06V`
    D
    `-0.618V`
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