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trans-But-2-ene reacts with cold dilute ...

trans-But`-2-`ene reacts with cold dilute `KMnO_(4)` solution to yield

A

butane`-2,3-`dione

B

`(+-)`butan`-2-`ol

C

meso-butane`2-,3-`diol

D

`(+-)`butane`-2,3-`diol

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The correct Answer is:
To solve the question regarding the reaction of trans-But-2-ene with cold dilute KMnO₄, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of trans-But-2-ene**: - trans-But-2-ene has the following structure: ``` CH3-CH=CH-CH3 ``` - The double bond is between the second and third carbon atoms, and the two methyl groups (CH3) are on opposite sides of the double bond. 2. **Understand the Reaction with Cold Dilute KMnO₄**: - Cold dilute KMnO₄ is known to perform syn-dihydroxylation, which means it adds two hydroxyl (OH) groups across the double bond in a syn fashion (both groups add to the same side). 3. **Mechanism of the Reaction**: - When trans-But-2-ene reacts with cold dilute KMnO₄, the double bond is broken, and two hydroxyl groups are added to the carbons involved in the double bond. - The reaction proceeds through the formation of a cyclic manganate ester intermediate. 4. **Product Formation**: - Since the addition is syn, both OH groups will be added to the same side of the double bond. - The resulting product will have the following structure: ``` CH3-CHOH-CHOH-CH3 ``` - This compound is 2,3-butanediol. 5. **Stereochemistry**: - The product formed will be a racemic mixture because the addition of OH groups can occur from either side of the double bond, leading to two enantiomers (R and S forms of 2,3-butanediol). 6. **Final Answer**: - The product of the reaction of trans-But-2-ene with cold dilute KMnO₄ is a racemic mixture of 2,3-butanediol. ### Summary: The reaction of trans-But-2-ene with cold dilute KMnO₄ yields a racemic mixture of 2,3-butanediol.

To solve the question regarding the reaction of trans-But-2-ene with cold dilute KMnO₄, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of trans-But-2-ene**: - trans-But-2-ene has the following structure: ``` CH3-CH=CH-CH3 ...
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Knowledge Check

  • cis-But -2- ene on reaction with cold dilute KMnO_(4) solution yields

    A
    `(+)-`butane`-2,3`-diol
    B
    `(-)`butane-`2,3`-diol
    C
    `(+-)`butane`-2,3-`diol
    D
    meso-butane`-2,3-`diol
  • Ethene reacts with cold dilute KMnO_(4) to produce

    A
    ethane-`1,2`-dial
    B
    ethanol
    C
    ethanal
    D
    ethane -`1,2`-diol
  • Cyclohexene reacts with cold dilute alkaline KMnO_4 to yield

    A
    cis-1,2-cyclohexanediol
    B
    trans-1,2-cyclohexanediol
    C
    cyclohexanone
    D
    hexane-1,6-dial
  • R SHARMA-STEREOCHEMISTRY-Level III
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    2. Consider the following configuration (A),(B) and (C ). (A) Whic...

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    3. The chemical properties of enantiomer are the same towards achiral (...

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    4. Which fo the following stereosimers represent meso compounds?

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    6. Cyclohexene on reaction with Br(2)in C CI(4) yields

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    7. Consider the following reaction sequence The final product (III)...

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    8. trans-But-2-ene reacts with cold dilute KMnO(4) solution to yield

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