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Cyclohexene on raction with cold dilute ...

Cyclohexene on raction with cold dilute `KMnO_(4)` solutioon gives

A

`(+-)-`trans`-1,2`-cyclohexanediol

B

`1,2-`cyclohexanediol

C

cis`-1,2-`cyclohexanediol

D

trans`-1,2-cyclohexanediol

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To solve the question regarding the reaction of cyclohexene with cold dilute KMnO4, we can follow these steps: ### Step 1: Identify the Reactants We start with cyclohexene, which is an alkene with the molecular formula C6H10. It has a double bond between two carbon atoms in a six-membered ring. **Hint:** Remember that cyclohexene is a cyclic compound with a double bond, which makes it reactive towards certain reagents. ### Step 2: Understand the Reaction Conditions The reaction is carried out with cold dilute KMnO4. KMnO4 is known for its ability to perform syn-dihydroxylation of alkenes. This means that it adds hydroxyl (OH) groups across the double bond in a syn fashion (on the same side). **Hint:** Syn-dihydroxylation results in the addition of two hydroxyl groups to the same side of the double bond. ### Step 3: Perform the Reaction When cyclohexene reacts with cold dilute KMnO4, the double bond opens up, and two hydroxyl groups are added to the carbons that were involved in the double bond. This results in the formation of a diol. **Hint:** Visualize the addition of OH groups to the double bond; they will be added to the same side of the ring. ### Step 4: Analyze the Product Structure After the reaction, we get a compound where the two hydroxyl groups are added to adjacent carbon atoms (1 and 2 positions) in a cis configuration. This results in a meso compound because it has a plane of symmetry. **Hint:** A meso compound has multiple stereocenters but is achiral due to its internal symmetry. ### Step 5: Name the Product The product formed is 1,2-cyclohexanediol. Since the hydroxyl groups are added in a cis configuration, we can refer to it as cis-1,2-cyclohexanediol. **Hint:** When naming diols, indicate the positions of the hydroxyl groups and whether they are in a cis or trans configuration. ### Final Answer The product of the reaction of cyclohexene with cold dilute KMnO4 is **cis-1,2-cyclohexanediol**. ### Summary of Steps: 1. Identify the reactant (cyclohexene). 2. Understand the reaction conditions (cold dilute KMnO4). 3. Perform the reaction (syn-dihydroxylation). 4. Analyze the product structure (meso compound). 5. Name the product (cis-1,2-cyclohexanediol).

To solve the question regarding the reaction of cyclohexene with cold dilute KMnO4, we can follow these steps: ### Step 1: Identify the Reactants We start with cyclohexene, which is an alkene with the molecular formula C6H10. It has a double bond between two carbon atoms in a six-membered ring. **Hint:** Remember that cyclohexene is a cyclic compound with a double bond, which makes it reactive towards certain reagents. ### Step 2: Understand the Reaction Conditions ...
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Cyclohexene on reaction with cold alkaline KMnO_4 forms,

One mole of hydrocarbon (A) reacts with one mole of bromine giving a dibromocompound C_(5)H_(10)Br_(2) . Substance (A) on treatment with cold, dilute alkaline KMnO_(4) solution forms a compound C_(5)H_(12)O_(2) . On ozonolysis, (A) gives equimolar quantities of propanone and ethanal. Deduce the structural formula of (A)

Knowledge Check

  • cis-But -2- ene on reaction with cold dilute KMnO_(4) solution yields

    A
    `(+)-`butane`-2,3`-diol
    B
    `(-)`butane-`2,3`-diol
    C
    `(+-)`butane`-2,3-`diol
    D
    meso-butane`-2,3-`diol
  • Ethene reacts with cold dilute KMnO_(4) to produce

    A
    ethane-`1,2`-dial
    B
    ethanol
    C
    ethanal
    D
    ethane -`1,2`-diol
  • Cyclohexene on oxidation with conc. KMnO_(4) forms

    A
    `HOOC-(CH_(2))_(4)-COOH`
    B
    `HOOC-(CH_(2))_(3)-COOH`
    C
    `HOOC-(CH_(2))_(3)-overset(O)overset(||)(C)-CH_(3)`
    D
    `HOOC-(CH_(2))_(4)-CH_(3)`
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