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Benzoylation of phenol with benzoyl chlo...

Benzoylation of phenol with benzoyl chloride in the presence of dilute `NaOH` gives phenyl benzoate. This reaction is an example of

A

Friedel - Crafts reaction

B

Reimer - Tiemann reaction

C

Clasien - Schmidt reaction

D

Schotten - Baumann reaction

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To solve the question regarding the benzoylation of phenol with benzoyl chloride in the presence of dilute NaOH, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are phenol (C6H5OH) and benzoyl chloride (C6H5COCl). 2. **Understand the Reaction Conditions**: - The reaction takes place in the presence of dilute sodium hydroxide (NaOH), which provides a basic medium. 3. **Mechanism of the Reaction**: - In a basic medium, the hydroxide ion (OH-) from NaOH acts as a nucleophile. - The lone pair of electrons on the oxygen atom of phenol attacks the carbonyl carbon of benzoyl chloride, leading to the formation of a tetrahedral intermediate. 4. **Formation of the Intermediate**: - The tetrahedral intermediate is formed when the oxygen atom of phenol attacks the carbonyl carbon of benzoyl chloride. This results in the displacement of the chloride ion (Cl-). 5. **Elimination of the Leaving Group**: - The intermediate collapses, leading to the elimination of the chloride ion and the formation of the ester bond. 6. **Final Product Formation**: - The final product of this reaction is phenyl benzoate (C6H5COOC6H5), which is an ester formed from the reaction of phenol and benzoyl chloride. 7. **Identify the Type of Reaction**: - The reaction is classified as a **Scotton-Baumann reaction**, which specifically refers to the benzoylation of phenol. ### Conclusion: The benzoylation of phenol with benzoyl chloride in the presence of dilute NaOH gives phenyl benzoate, and this reaction is an example of the **Scotton-Baumann reaction**. ---

To solve the question regarding the benzoylation of phenol with benzoyl chloride in the presence of dilute NaOH, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are phenol (C6H5OH) and benzoyl chloride (C6H5COCl). 2. **Understand the Reaction Conditions**: ...
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