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On the basis of the following observatio...

On the basis of the following observations made with aqueous solutions, how many of them have 6 secondary valencies ?
`{:(" Formula","Moles of AgCl precipitated per mole of the compounds with excess" AgNO_(3)),((a) PdCl_(2).4NH_(3)," "2),((b) NiCl_(2).6H_(2)O," "2),((c) PtCl_(4).2HCl," "0),((d) CoCl_(3).4NH_(3)," "1),((e) PtCl_(2).2NH_(3)," "0):}`

Text Solution

Verified by Experts

(i) Formula = `[Pd(NH_(3))_(4)]Cl_(2)`, Secondary valencies = 4
(ii) Formula = `[Ni(H_(2)O)_(6)]Cl_(2)`, Secondary valencies = 6
(iii) Formula = `H_(2)[PtCl_(6)]`, Secondary valencies = 6
(iv) Formula = `[Co(NH_(3))_(4)Cl_(2)]Cl`, Secondary valencies = 6
(v) Formula = `[Pt(NH_(3))_(2)Cl_(2)]`, Secondary valencies = 4
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Knowledge Check

  • On the basis of the following observations made with acqueous solutions. In which of the following complexes the central metal atom exhibits secondary valency is six

    A
    `I,ii,iv`
    B
    `ii,iii,iv`
    C
    `ii,iv,v`
    D
    `I,iv,v`

  • The no. of moles of AgCl precipitated when excess of AgNO_(3) is mixed with one mole of [Cr(NH_(3))_(3)Cl_(3)] is

    A
    `0`
    B
    `1`
    C
    `2`
    D
    `3`

  • How many moles of AgCl is precipitated, when excess of AgNO_(3) is added to the one mole of CoCl_(3) .4NH_(3) (green) :

    A
    1
    B
    3
    C
    2
    D
    4

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    When a co-ordination compound COCl_(3).4NH_(3) is mixed with AgNO_(3) . 1 mole of AgCl is precipitated per mole of the compound. Write IUPAC name of the complex.

    When a coordination compound CrCl_3. 6H_2O is mixed with AgNO_3 , 2 moles of AgCl are precipitated per mole of the compound. Write structural formula of the complex.

    When a co-ordination compound CrCl_(3).6H_(2)O is mixed with AgNO_(3) , 2 moles of AgCl are precipitated per mole of the compound. Write IUPAC name of the complex.

    which of the folllowing coordination compound will give precipitate with an aqueous solution of AgNO_(3) ?

    When one mole of CoCl_(3).5NH_(3) was treated with excess of silver nitrate solution, 2 mol of AgCl was precipitated. The formula of the compound is:

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