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Ethers can be prepared by Williamson syn...

Ethers can be prepared by Williamson synthesis in which an alkyl halide is reacted with sodium alkoxide. Di-tert-buty ether can't be prepared by this method. Explain

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Williamson's synthesis occurs by `S_(N)2` mechanism in which sodium alkoxide reacts with an alkyl halide. Now to prepare di-tert-butyl ether, sodium tert-butoxide must be reacted with tert-butyl bromide. Since `3^(@)` alkyl halides prefer to undergo elimination rather than substitution, therefore, sodium tert-butoxide reacts with tert-butyl bromide and favours elimination to form isobutylene rather than substitution to form di-tert-butyl ether.

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Ethers can not be prepared by :

tert-Butyl ethyl ether can't be prepared by which reaction?

Why di tert-butyl ether cannot be prepared by Williamson synthesis ?

Di-t- butyl ether is prepared best by the reaction

Allyl phenyl ether can be prepared by heating:

An alkyl halide reacts with sodium in the presence of ether to yield

Knowledge Check

  • Ethers can not be prepared by :

    A
    Heating alkyl halide with dry silver oxide
    B
    Heating alkyl halide with ammonical KOH
    C
    Heating alkyl halide with pottasium alkoxide
    D
    Heating an excess of alcohol with alumina under pressure
  • tert-Butyl ethyl ether can't be prepared by which reaction?

    A
    `"tert"-"Butanol"+"ethanol"overset(H^(+))rarr`
    B
    `"tert - Butyl bromide"+"sodium ethoxide"rarr`
    C
    `"Sodium tert - butoxide "+"ethyl bromide"rarr`
    D
    `"Isobutene "+"ethanol"overset(H^(+))rarr`
  • Allyl phenyl ether can be prepared by

    A
    `CH_(2)=CH-CH_(2)-ONa+C_(6)H_(5)CH_(2)-Br`
    B
    `C_(6)H_(5)-CH=CH-Br+CH_(3)-ONa`
    C
    `CH_(2)=CH-ONa+C_(6)H_(5)Br`
    D
    `CH_(2)=CH-CH_(2)-Br+C_(6)H_(5)ONa`
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    13. Dipole moment of phenol is smaller than that of methanol. Why ?

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    15. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

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