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Why is the C-O-H bond angle in alcohols ...

Why is the `C-O-H` bond angle in alcohols slightly less than the tetrahedral angle whereas the C-O-C bond angle in ether is slightly greater?

Text Solution

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The oxygen atom in both alcohols and ethers in `sp^(3)`-hydridized. However, due to greater

lone pair-lone pair than bond pair-bond pairr repulsion, the C-O-H bond angle in alcohols is slightly lowerr `(109^(@))` than the normal tetrahderal angle of `109^(@)-28'`. however, in ether C-O-C bond angle is slightly greater `(110^(@))` than tetrahedral angle due to repulsion between the two bulkyl R groups.
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The R-O-R bond angle in ether is

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Knowledge Check

  • The R-O-R bond angle in ether is

    A
    `90^(@)`
    B
    `104^(@)`
    C
    `110^(@)`
    D
    `180^(@)`
  • Bond angle in alcohols is slightly less than the tetrahedral angle because of

    A
    electronegativity of oxygen
    B
    H-bonding
    C
    repulsion between the unshared electron pairs of oxygen
    D
    none of these.
  • The H-O-H bond angle in water is

    A
    `109.5^@`
    B
    `107^@`
    C
    `102^@`
    D
    `104.5^@`
  • PRADEEP-ALCOHOLS, PHENOLS AND ETHERS-NCERT EXEMPLAR PROBLEMS WITH ANSWERS, HINTS AND SOLUTION (SHORT ANSWER QUESTIONS)
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    4. Write the structures of the isomers of alcohols with molecular formula...

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    5. Explain why is OH group in phenols more strongly held as compared to O...

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    6. Explain why nucleophilic substitution reactions are not very common in...

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    7. Preparation of alcohols from alkenes involves the electrophilic attack...

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    8. Explain why is O=C=O non polar while R-O-R is polar ?

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    9. Why is the reactivity of all the three classes of alcohols with conc. ...

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    10. Write steps to carry out the conversion of phenol to aspirin.

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    11. Nitration is an example of aromatic electrophilic substitution and its...

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    12. In Kolbe's reactio insteaded of phenol, phenoxide ion is treated with ...

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    13. Dipole moment of phenol is smaller than that of methanol. Why ?

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    14. Ethers can be prepared by Williamson synthesis in which an alkyl halid...

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    15. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

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    16. Explain why low molecular mass alcohols are soluble in water ?

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    17. Explain why p-nitrophenol is more acidic than phenol ?

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    18. Explain why alcohols and ethers of comparable molecular mass have diff...

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    19. The carbon-oxygen bond in phenol is slightly stronger than that in met...

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    20. Arrange water, ethanol and phenol in increasing order of acidity and g...

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