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pK(a) of chloroacetic acid is lower than...

`pK_(a)` of chloroacetic acid is lower than `pK_(a)` of acetic acid. Explain.

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To explain why the \( pK_a \) of chloroacetic acid is lower than that of acetic acid, we can follow these steps: ### Step 1: Understand the Structures - **Acetic Acid**: The molecular formula is \( CH_3COOH \). - **Chloroacetic Acid**: The molecular formula is \( CH_2ClCOOH \). ### Step 2: Identify the Conjugate Bases - When acetic acid loses a proton (\( H^+ \)), it forms the acetate ion \( CH_3COO^- \). ...
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Explore conceptually related problems

Account for the following : (i) Benzoic acid does not undergo Friedel crafts reaction (ii) Pk_(a) value of chloroacetic acid is lower than Pk_(a) of acetic acid.

The pK_a value of formic acid is smaller than that of acetic acid.

pK_a value of 4- nitrobenzoic acid to lower than that of benzoic acid . Explain

(b) Explain why chloroacetic acid is a stronger acid than acetic acid.

Account for the following : (a) Aromatic carboxylic acids do not undergo Friedel-Crafts reaction. (b) pK_(a) value of 4-nitrobenzoic acid is lower than that of benzoic acid .

Knowledge Check

  • Which acid has lowest pK_(a)

    A
    `p-`Methoxybenzoic acid
    B
    `p-`Chlorobenzoic acid
    C
    `p-`Aminobenzoic acid
    D
    `p-`toluic acid
  • Assertion: The pK_(a) of acetic acid is lower than that of phenol. Reason: Phenoxide ion is more resonance stabilized than acetate ion.

    A
    if both assertion and reson are true, and reason is the true explanation of the assertion.
    B
    If both assertion and reason are true, but reason is not the true explanation of the assertion.
    C
    if assertion is true, but reason is false.
    D
    If both assertion and reason are false.
  • Assertion: The pK_(a) of acetic acid is lower than that of phenol Reason: Phenoxide ion is more resonance stabilised.

    A
    If both assertion and reason are true and reason is a correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not a correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If assertion and reason both are false.
  • PRADEEP-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -ADDITIONAL QUESTIONS (VERY SHORT ANSWER QUESTIONS)
    1. How is CH(3)OH conveted into CH(3)COOH (in one step)?

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    2. Why is benzoic acid less soluble in water than acitic acid?

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    3. Arrange the following in increasing order of their boiling points. C...

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    4. Arrange the following in decreasing order of boiling point. (i) CH(3...

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    5. What is meant by 'acidity constant', K(a)? How is it expressed?

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    6. What makes ethanoic acid a stronger acid than ethanol?

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    7. What makes acetic acid a stronger acid than phenol?

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    8. pK(a) of chloroacetic acid is lower than pK(a) of acetic acid. Explain...

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    9. Arrange the following as stated : 'Increasing order of acidic streng...

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    10. Why is pKa of F-CH(2)COOH lower than that of Cl-CH(2)COOH?

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    11. How would you distinguish experimentally between an alcohol and a carb...

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    12. Predict the product of the following reaction CH(3)COONa underset(De...

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    13. Which one of the following is an example of Hell-Volhard Zelinsky reac...

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    14. Why HCOOH does not give HVZ reaction but CH(3)COOH does ?

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    15. Name the reagent used to convert carboxylic acids directly to the corr...

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    16. Account for the following : (i) Benzoic acid does not undergo Friede...

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    17. What is vinegar ?

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    18. Mention a chemical property in which formic acid (methanoic acid) diff...

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    19. How will you convert an acid into an ester without using an alcohol?

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    20. Why is ester hydrolysis slow in the beginning and becomes faster after...

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