Home
Class 11
CHEMISTRY
The magnetic moment of .25Mn in ionic st...

The magnetic moment of `._25Mn` in ionic state is `sqrt(15)B.M`, then Mn is in:

A

1

B

2

C

3

D

4

Text Solution

Verified by Experts

The correct Answer is:
4

`25^(Mn)-[Ar]3d^(5)4s^(2)`

Given `sqrt(n(n+2))=sqrt(15)rArrn=3`
Hence to have `'3'` unpaired electrons `Mn` must be in `'+4'` state
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • AROMATIC COMPOUNDS

    RESONANCE|Exercise PART-II : JEE (MAIN)|1 Videos
  • CHEMICAL BONDING

    RESONANCE|Exercise Inorganic chemistry (Chemistry Bonding)|49 Videos

Similar Questions

Explore conceptually related problems

The magnetic moment of M^(+) (atomic number = 25 is sqt(15) BM .The number of unpaired electron and the value of x respectivekly are

If hydrogen atoms (in the ground state ) are passed through an homogeneous magnetic field, the beam is split into two parts. This interaction with the magnetic field shows that the atoms must have magnetic moment. However, the moment cannot be due to the orbital angular momentum since l=0. Hence one must assume existence of intrinsic angular momentum, which as the experiment shows, has only two permitted orientations. Spin of the electron produce angular momentum equal to S=sqrt(s(s+1))(h)/(2pi) where S=+(1)/(2) . Total spin of an atom = +(n)/(2) " or "-(n)/(2) where n is the number of unpaired electrons. The substance which contain species with unpaired electrons in their orbitals behave as paramagnetic substances. The paramagnetism is expressed in terms of magnetic moment. The magnetic moment of an atom mu_(s)sqrt(s(s+1))(eh)/(2pimc)=sqrt((n)/(2)((n)/(2)+1))(eh)/(2pimc)" "s=(n)/(2) impliesmu_(s)=sqrt(n(n+1)) B.M. 1. B.M. (Bohr magneton)= (eh)/(4pimc) If magnetic moment is zero the substance is diamagnetic. If an ion of _(25)Mn has a magnetic moment of 3.873 B.M. Then oxidation state of Mn in ion is :

Knowledge Check

  • The magnetic moment of ._(25)Mn in ionic state is sqrt(15) B.M, then Mn is in:

    A
    `+2` state
    B
    `+3` state
    C
    `+4` state
    D
    `+5` state
  • The magneitc moment of ._(25)Mn in ionic state is 4.83 B.M., then Mn is in :

    A
    `+2` state
    B
    `+3` state
    C
    `+4` state
    D
    `+5` state
  • The magneitc moment of ._(25)Mn in ionic state is 4.83 B.M., then Mn is in :

    A
    `+2` state
    B
    `+3` state
    C
    `+4` state
    D
    `+5` state
  • Similar Questions

    Explore conceptually related problems

    The spin only magnetic moment of Mn^(4+) ion is nearly

    The spin only magnetic moment of Mn^(4+) ion is nearly

    Choose the most appropriate options. The magnetic moment of M^(x +) (atomic number = 25) is sqrt 15 BM. Then, the oxidation number x of M is :

    Spin only magnetic moment of Mn^(4+) ion is nearly

    The oxidation state of Mn in potassium manganate is :