Statement -1 : Hydrogen of NCl(3) gives...

Statement -1 : Hydrogen of `NCl_(3)` gives `NH_(4)OH` and `HOCl` while `PCl_(3)` on hydrolysis gives `H_(3)PO_(3)` and HCl.
Statement -2 : The difference is due to the change in polarity of `P^(+sigma)-CI^(-sigma)` bond in `PCI_(3)` in contrast to `N^(-sigma)-CI^(+sigma)` bond in `NCI_(3)`.

Statement -1 is true , Statement-2 is true, Statement-2 is a correct explantion for Statement -1.

Statement -1 is true, Statement- 2 is false.

Statement -1 is False, Statement- 2 is True.

Statement -1 and Statement- 2 both are False.

Verified by Experts

The correct Answer is:

Through coordinate bond formation.

P BLOCK ELEMENTS
RESONANCE|Exercise ALP PART 1 Comprehension # 1 OBJECTIVE|8 Videos
P BLOCK ELEMENTS
RESONANCE|Exercise ALP PART 1 Comprehension # 2 OBJECTIVE|1 Videos
P BLOCK ELEMENTS
RESONANCE|Exercise ALP PART 1 OBJECTIVE|99 Videos
NUCLEAR CHEMISTRY
RESONANCE|Exercise STAGE-II|1 Videos
P-BLOCK ELEMENT (BORON AND CARBON FAMILY)
RESONANCE|Exercise PART - III : OLYMPIAD PROBLEMS (PREVIOUS YEARS) STAGE - V (INTERNATIONAL CHEMISTRY OLYMPIAD (IChO)) Problem 3|8 Videos

Assertion: Hydrolysis of NCl_(3) gives NH_(3) and HOCl , white PCI_(3) on hydrolysis gives H_(3)PO_(3) and HCI Reason: The difference is due to the change in polarity of overset(delta+)(P-)overset(delta-)(CI) bond in NCI_(3) in contrast to overset(delta-)(N-)overset(delta+)(CI) bond in NCI_(3)

Both A and R are correct and R is the correct explanation of A

Both A and R are correct and R is not the correct explanation of A

A is correct R is wrong

A is wrong R is correct

` 1 sigma and 3 pi `

`2 sigma and 2pi`

`3 sigma and 2pi`

`3 sigma and 3pi`