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Elevation of boiling point of 1 molar aq...

Elevation of boiling point of 1 molar aqueous glucose solution `("density"=1.2g//ml)` is

A

`"K"_("b")`

B

1.20 `"K"_("b")`

C

1.02`"K"_("b")`

D

0.98`"K"_("b")`

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To solve the problem of finding the elevation of the boiling point of a 1 molar aqueous glucose solution with a density of 1.2 g/ml, we can follow these steps: ### Step 1: Determine the number of moles of glucose Since the solution is 1 molar, it means there is 1 mole of glucose in 1 liter (1000 ml) of solution. **Hint:** Molarity (M) is defined as moles of solute per liter of solution. ### Step 2: Calculate the mass of glucose The molar mass of glucose (C6H12O6) is approximately 180 g/mol. Therefore, the mass of 1 mole of glucose is: \[ \text{Mass of glucose} = 1 \, \text{mol} \times 180 \, \text{g/mol} = 180 \, \text{g} \] **Hint:** To find the mass of a substance, multiply the number of moles by its molar mass. ### Step 3: Calculate the total mass of the solution Using the density of the solution (1.2 g/ml), we can find the total mass of 1 liter (1000 ml) of the solution: \[ \text{Mass of solution} = \text{Density} \times \text{Volume} = 1.2 \, \text{g/ml} \times 1000 \, \text{ml} = 1200 \, \text{g} \] **Hint:** The mass of a solution can be found by multiplying its density by its volume. ### Step 4: Calculate the mass of the solvent (water) To find the mass of the solvent (water), we subtract the mass of the solute (glucose) from the total mass of the solution: \[ \text{Mass of solvent} = \text{Mass of solution} - \text{Mass of solute} = 1200 \, \text{g} - 180 \, \text{g} = 1020 \, \text{g} \] **Hint:** The mass of the solvent is the total mass of the solution minus the mass of the solute. ### Step 5: Convert the mass of the solvent to kilograms Since molality is defined in terms of kilograms of solvent, we convert the mass of the solvent from grams to kilograms: \[ \text{Mass of solvent in kg} = \frac{1020 \, \text{g}}{1000} = 1.02 \, \text{kg} \] **Hint:** To convert grams to kilograms, divide by 1000. ### Step 6: Calculate the molality of the solution Molality (m) is defined as the number of moles of solute per kilogram of solvent: \[ \text{Molality} = \frac{\text{Number of moles of solute}}{\text{Mass of solvent in kg}} = \frac{1 \, \text{mol}}{1.02 \, \text{kg}} \approx 0.9804 \, \text{mol/kg} \] **Hint:** Molality is calculated using the formula: m = moles of solute / kg of solvent. ### Step 7: Calculate the elevation of boiling point (ΔTb) The elevation of boiling point can be calculated using the formula: \[ \Delta T_b = K_b \times m \] Where \( K_b \) is the ebullioscopic constant for water (approximately 0.512 °C kg/mol). Substituting the values: \[ \Delta T_b = 0.512 \, \text{°C kg/mol} \times 0.9804 \, \text{mol/kg} \approx 0.501 \, \text{°C} \] **Hint:** The elevation in boiling point is found by multiplying the ebullioscopic constant by the molality of the solution. ### Final Answer The elevation of the boiling point of a 1 molar aqueous glucose solution is approximately \( 0.501 \, \text{°C} \).

To solve the problem of finding the elevation of the boiling point of a 1 molar aqueous glucose solution with a density of 1.2 g/ml, we can follow these steps: ### Step 1: Determine the number of moles of glucose Since the solution is 1 molar, it means there is 1 mole of glucose in 1 liter (1000 ml) of solution. **Hint:** Molarity (M) is defined as moles of solute per liter of solution. ### Step 2: Calculate the mass of glucose ...
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Knowledge Check

  • Elevation in boiling point of a molar (1M) glucose solution (d=1.2 g ml_(-1)) is

    A
    `1.34K_(b)`
    B
    `0.98K_(b)`
    C
    `2.40K_(b)`
    D
    `K_(b)`
  • The relative decrease in VP of an aqueous glucose dilute solution is found to be 0.018 . Hence, the elevation in boiling point is (it is given 1 molal aqueous urea solution boils at 100.54^@)C at 1 atm pressure)

    A
    `0.018^(@)`
    B
    `0.18^(@)`
    C
    `0.54^(@)`
    D
    `0.03^(@)`
  • Relative decrease in vapour pressure of an aqueous glucose dilute solution is found to be 0.018. Hence, elevation in boiling point is : (It is given that 1 molal aqueous urea solution boils at 100.54^@C at 1 atm pressure)

    A
    0.018 K
    B
    0.18 K
    C
    0.54 K
    D
    0.03 K
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