1 mole of liquid A and 9 moles of liquid B are mixed to form a solution. If `"P"_("B")^(@)=400"mm"` of Hg and `"P"_("A")^(@)=20 "mm"` of Hg at a temperature 'T' and normal boiling point of liquid B is 300K then answer the questions that follow. Given data: `"K"_("b")=2.7"K kg mol"^(-1),` Molar mass of B=100 It is observed that pressure of vapour above the solution at 'T' Kelvin is 350 mm Hg. The true statement is :
A
The liquids form ideal solution.
B
The solute- solvent interactions are weaker than solvent- solvent or solute- solute interactions.
C
The volume of final solution will be lower than sum of individual volumes
D
The enthalpy change due to mixing will be zero.
Text Solution
Verified by Experts
The correct Answer is:
C
P=350 mm of Hg `"P"_("T")="P"_("A")^(@)"x"_("A")+"P"_("B")^(@)"x"_("B")` `20xx1/10+400xx9/10=362` `"P"lt"P"_("T")` -ve deviation `Delta"V"_("mix")lt0`
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Knowledge Check
1 mole of liquid A and 9 moles of liquid B are mixed to form a solution. If "P"_("B")^(@)=400"mm" of Hg and "P"_("A")^(@)=20 "mm" of Hg at a temperature 'T' and normal boiling point of liquid B is 300K then answer the questions that follow. Given data: "K"_("b")=2.7"K kg mol"^(-1), Molar mass of B=100 If 'A' is assumed to be perfectly non volatile then what will be normal boiling point of the solution.
A
300
B
300.3
C
303
D
300.003
1 mole of liquid A and 9 moles of liquid B are mixed to form a solution. If "P"_("B")^(@)=400"mm" of Hg and "P"_("A")^(@)=20 "mm" of Hg at a temperature 'T' and normal boiling point of liquid B is 300K then answer the questions that follow. Given data: "K"_("b")=2.7"K kg mol"^(-1), Molar mass of B=100 If 'A' is perfectly non volatile and it dimerises to and extent of 60% then what will be the vapour pressure of the solution.
A
`360mm Hg`
B
`3600/9.7" mm Hg"`
C
`4000/9.7"mm Hg"`
D
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Pressure over ideal binary liquid mixture containing 10 moles each of liquid A and B is gradually decreased isothermally. If "P"_("A")^(@)=200"mm Hg " "and"" P"_("B")^(@)=100"mm Hg, " find the pressure at which half of the liquid is converted into vapour.
A
`150` mm Hg
B
166.5 mmHg
C
133 mmHg
D
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