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Potassium dichromate (K(2)Cr(2)O(7)) is ...

Potassium dichromate `(K_(2)Cr_(2)O_(7))` is an orange coloured compound , very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromite `(FeCr_(2)O_(4))` ore according to the following reactions:
(1) Fusion of chromite ore with sodium carbonate in excess of air.
`FeCr_(2)O_(4) + Na_(2)CO_(3) + O_(2) rarr Na_(2)CrO_(4)+Fe_(2)O_(3) +CO_(2)`
(2) Acidifing filtered sodium chromate solution with sulphuric acid.
`Na_(2)CrO_(4) + H_(2)SO_(4) rarr Na_(2)Cr_(2)O_(7) + Na_(2)SO_(4) + H_(2)O`
(3) Treating sodium dichormate with potassium choride .
`Na_(2)Cr_(2)O_(7) + KCl rarr K_(2)Cr_(2)O_(7) + NaCl`
If the number of moles of reactant available for reaction are : `[FeCr_(2)O_(4)=0.25 "moles" , O_(2)=0.35 "moles", Na_(2)CO_(3)=0.60 "moles", H_(2)SO_(4)=0.2 "moles", KCl=0.4 "moles"]` , then the maximum number of moles of `K_(2)Cr_(2)O_(7)` , that can be produced is :

A

0.05 moles

B

0.1 moles

C

0.2 moles

D

0.5 moles

Text Solution

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The correct Answer is:
C
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Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound, very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromit (FeCr_(2)O_(4)) ore according to the following reactions: (a) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4)+Na_(2)CO_(3)+O_(2) to Na_(2)CrO_(4)+Fe_(2)O_(3)+CO_(2) (b) Acidifying filetered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4)+H_(2)SO_(4) to Na_(2)Cr_(2)O_(7)+Na_(2)SO_(4)+H_(2)O (c) Treating sodium dichromate with potassium chloride. Na_(2)Cr_(2)O_(7)+KCl to K_(2)Cr_(2)O_(7)+NaCl Answer the following questions using above information. If whole of the chromite ore given in the previous question gets consumed and sufficient amount of rest of the reactants are given, then the mass of K_(2)Cr_(2)O_(7) obtained is :

Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound, very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromit (FeCr_(2)O_(4)) ore according to the following reactions: (a) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4)+Na_(2)CO_(3)+O_(2) to Na_(2)CrO_(4)+Fe_(2)O_(3)+CO_(2) (b) Acidifying filetered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4)+H_(2)SO_(4) to Na_(2)Cr_(2)O_(7)+Na_(2)SO_(4)+H_(2)O (c) Treating sodium dichromate with potassium chloride. Na_(2)Cr_(2)O_(7)+KCl to K_(2)Cr_(2)O_(7)+NaCl Answer the following questions using above information. If you are intially provided with 224 gm of pure chromite ore and 169.6gm of sodium carbonate, the minimum volume of air required at 1 atm and 273 K to consume at least one of the reactant completely, if aire contains 20% by volume of oxygen gas is :

Knowledge Check

  • Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound, very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromit (FeCr_(2)O_(4)) ore according to the following reactions: (a) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4)+Na_(2)CO_(3)+O_(2) to Na_(2)CrO_(4)+Fe_(2)O_(3)+CO_(2) (b) Acidifying filetered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4)+H_(2)SO_(4) to Na_(2)Cr_(2)O_(7)+Na_(2)SO_(4)+H_(2)O (c) Treating sodium dichromate with potassium chloride. Na_(2)Cr_(2)O_(7)+KCl to K_(2)Cr_(2)O_(7)+NaCl Answer the following questions using above information. If the number of moles of reactants available for reactions are: { FeCr_(2)O_(4) =0.25 moles, O_(2) =0.35 moles, Na_(2)CO_(3) =0.60 moles, H_(2)SO_(4) =0.2 mol,es, KCl=0.1 moles}, then the maximum number of moles of K_(2)Cr_(2)O_(7) , that can be produced is :

    A
    0.05 moles
    B
    0.1 moles
    C
    0.2moles
    D
    0.5moles
  • Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound , very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromite (FeCr_(2)O_(4)) ore according to the following reactions: (1) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4) + Na_(2)CO_(3) + O_(2) rarr Na_(2)CrO_(4)+Fe_(2)O_(3) +CO_(2) (2) Acidifing filtered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4) + H_(2)SO_(4) rarr Na_(2)Cr_(2)O_(7) + Na_(2)SO_(4) + H_(2)O (3) Treating sodium dichormate with potassium choride . Na_(2)Cr_(2)O_(7) + KCl rarr K_(2)Cr_(2)O_(7) + NaCl If whole of the chormite ore given in the previous question gets consumed and sufficient amount of rest of the reactants are given, then the mass of K_(2)Cr_(2)O_(7) obtained is:

    A
    14.7 gm
    B
    7.35 gm
    C
    73.5 gm
    D
    147 gm
  • Potassium dichromate (K_(2)Cr_(2)O_(7)) is an orange coloured compound , very frequently used in laboratory as an oxidising agent as well as in a redox titration. It is generally prepared from chromite (FeCr_(2)O_(4)) ore according to the following reactions: (1) Fusion of chromite ore with sodium carbonate in excess of air. FeCr_(2)O_(4) + Na_(2)CO_(3) + O_(2) rarr Na_(2)CrO_(4)+Fe_(2)O_(3) +CO_(2) (2) Acidifing filtered sodium chromate solution with sulphuric acid. Na_(2)CrO_(4) + H_(2)SO_(4) rarr Na_(2)Cr_(2)O_(7) + Na_(2)SO_(4) + H_(2)O (3) Treating sodium dichormate with potassium choride . Na_(2)Cr_(2)O_(7) + KCl rarr K_(2)Cr_(2)O_(7) + NaCl If you are initially provided with 224 gm of pure chromite ore and 169.6 gm of sodium carbonate , the minimum volume of air required at 1 atm and 273 K to consume at least one of the reactant completely, if air contains 20% by volume of oxygen gas is :

    A
    156.8 L
    B
    196 L
    C
    28 L
    D
    152.4 L
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