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The equilibrium constant K(p) for the fo...

The equilibrium constant `K_(p)` for the following rection at `191^(@)C` is 1.24. what is`K_(c)`?
`B(s)+(3)/(2)F_(2)(g)hArr(g)`

A

`6.7`

B

`0.61`

C

`8.30`

D

`7.6`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equilibrium constant \( K_c \) from the given \( K_p \), we can use the relationship between \( K_p \) and \( K_c \): \[ K_p = K_c \cdot (RT)^{\Delta n} \] where: - \( R \) is the ideal gas constant (0.0821 L·atm/(K·mol)), - \( T \) is the temperature in Kelvin, - \( \Delta n \) is the change in the number of moles of gas (moles of gaseous products - moles of gaseous reactants). ### Step 1: Calculate \( \Delta n \) For the reaction: \[ B(s) + \frac{3}{2}F_2(g) \rightleftharpoons BF_3(g) \] - Moles of gaseous products = 1 (from \( BF_3 \)) - Moles of gaseous reactants = \(\frac{3}{2}\) (from \( \frac{3}{2}F_2 \)) Thus, \[ \Delta n = \text{moles of products} - \text{moles of reactants} = 1 - \frac{3}{2} = 1 - 1.5 = -0.5 \] ### Step 2: Convert temperature to Kelvin The temperature given is \( 191^\circ C \). To convert it to Kelvin: \[ T(K) = 191 + 273 = 464 \, K \] ### Step 3: Substitute values into the equation Now we can substitute \( K_p \), \( R \), \( T \), and \( \Delta n \) into the equation: Given \( K_p = 1.24 \), \[ K_p = K_c \cdot (RT)^{\Delta n} \] Substituting the values: \[ 1.24 = K_c \cdot (0.0821 \cdot 464)^{-0.5} \] ### Step 4: Calculate \( RT \) Calculating \( RT \): \[ RT = 0.0821 \cdot 464 \approx 38.16984 \] ### Step 5: Calculate \( (RT)^{-0.5} \) Now calculate \( (RT)^{-0.5} \): \[ (RT)^{-0.5} = \frac{1}{\sqrt{38.16984}} \approx \frac{1}{6.17} \approx 0.162 \] ### Step 6: Solve for \( K_c \) Now, we can solve for \( K_c \): \[ 1.24 = K_c \cdot 0.162 \] \[ K_c = \frac{1.24}{0.162} \approx 7.65 \] Thus, rounding to two decimal places, we find: \[ K_c \approx 7.6 \] ### Final Answer The value of \( K_c \) is approximately **7.6**.
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Knowledge Check

  • The equilibrium constant K_(p) for the following reaction at 191^(@)C is 1.24. what is K_(C) ? B(s)+(3)/(2)F_(2)(g)hArrBF_(3)(g)

    A
    `6.7`
    B
    `0.61`
    C
    `8.30`
    D
    `7.6`
  • At 500 K, equilibrium constant, K_(c) , for the following reaction is 5. (1)/(2) H_(2) (g) + (1)/(2) I_(2) (g) hArr HI(g) What would be the equilibrium constant K_(c) for the reaction, 2 HI (g) hArr H_(2) (g) +I_(2) (g) ?

    A
    0.04
    B
    0.4
    C
    25
    D
    2.5
  • The following equilibrium constants were determined at 1120 K : 2CO(g)hArrC(s)+CO_(2)(g), , K_(p1)=10^(-114)atm^(-1) CO(g)+Cl_(2)(g)hArrCOCl_(2)(g), , K_(p2)=6xx10^(-3)atm^(-1) What is the equilibrium constant K_(c) for the foollowing reaction at 1120 K: C(s)+CO_(2)(g)+2Cl_(2)(g)hArr2COCl_(2)(g)

    A
    `3.31xx10^(11)M^(-1)`
    B
    `5.5xx10^(10)M^(-1)`
    C
    `5.51xx10^(6)M^(-1)`
    D
    None of these
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