The equilibrium constant `K_(p)` for the following rection at `191^(@)C` is 1.24. what is`K_(c)`? `B(s)+(3)/(2)F_(2)(g)hArr(g)`
A
`6.7`
B
`0.61`
C
`8.30`
D
`7.6`
Text Solution
AI Generated Solution
The correct Answer is:
To find the equilibrium constant \( K_c \) from the given \( K_p \), we can use the relationship between \( K_p \) and \( K_c \):
\[
K_p = K_c \cdot (RT)^{\Delta n}
\]
where:
- \( R \) is the ideal gas constant (0.0821 L·atm/(K·mol)),
- \( T \) is the temperature in Kelvin,
- \( \Delta n \) is the change in the number of moles of gas (moles of gaseous products - moles of gaseous reactants).
### Step 1: Calculate \( \Delta n \)
For the reaction:
\[
B(s) + \frac{3}{2}F_2(g) \rightleftharpoons BF_3(g)
\]
- Moles of gaseous products = 1 (from \( BF_3 \))
- Moles of gaseous reactants = \(\frac{3}{2}\) (from \( \frac{3}{2}F_2 \))
Thus,
\[
\Delta n = \text{moles of products} - \text{moles of reactants} = 1 - \frac{3}{2} = 1 - 1.5 = -0.5
\]
### Step 2: Convert temperature to Kelvin
The temperature given is \( 191^\circ C \). To convert it to Kelvin:
\[
T(K) = 191 + 273 = 464 \, K
\]
### Step 3: Substitute values into the equation
Now we can substitute \( K_p \), \( R \), \( T \), and \( \Delta n \) into the equation:
Given \( K_p = 1.24 \),
\[
K_p = K_c \cdot (RT)^{\Delta n}
\]
Substituting the values:
\[
1.24 = K_c \cdot (0.0821 \cdot 464)^{-0.5}
\]
### Step 4: Calculate \( RT \)
Calculating \( RT \):
\[
RT = 0.0821 \cdot 464 \approx 38.16984
\]
### Step 5: Calculate \( (RT)^{-0.5} \)
Now calculate \( (RT)^{-0.5} \):
\[
(RT)^{-0.5} = \frac{1}{\sqrt{38.16984}} \approx \frac{1}{6.17} \approx 0.162
\]
### Step 6: Solve for \( K_c \)
Now, we can solve for \( K_c \):
\[
1.24 = K_c \cdot 0.162
\]
\[
K_c = \frac{1.24}{0.162} \approx 7.65
\]
Thus, rounding to two decimal places, we find:
\[
K_c \approx 7.6
\]
### Final Answer
The value of \( K_c \) is approximately **7.6**.
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