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The order of bond strength among C-F, C-...

The order of bond strength among C-F, C-Cl, C-Br, C-1 is

A

`C-F gt C-CL gt C-Br gt C-I`

B

`C-F lt C-Cl lt C-Br lt C-I`

C

`C-F gt C-Cl lt C-Br lt C-I`

D

`C-F gt C-I lt C-Br ltC-I`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of bond strength among C-F, C-Cl, C-Br, and C-I bonds, we can analyze the electronegativity of the atoms involved and how it affects bond strength. Here’s a step-by-step solution: ### Step 1: Understand Electronegativity Electronegativity is a measure of an atom's ability to attract and hold onto electrons. The greater the difference in electronegativity between two bonded atoms, the stronger the bond tends to be due to increased ionic character. ### Step 2: Identify Electronegativity Values We need to know the electronegativity values of carbon and the halogens: - Carbon (C): 2.55 - Fluorine (F): 3.98 - Chlorine (Cl): 3.16 - Bromine (Br): 2.96 - Iodine (I): 2.66 ### Step 3: Calculate the Electronegativity Differences Now, we will calculate the difference in electronegativity for each bond: 1. **C-F**: 3.98 - 2.55 = 1.43 2. **C-Cl**: 3.16 - 2.55 = 0.61 3. **C-Br**: 2.96 - 2.55 = 0.41 4. **C-I**: 2.66 - 2.55 = 0.11 ### Step 4: Analyze the Differences The order of electronegativity differences is: - C-F: 1.43 - C-Cl: 0.61 - C-Br: 0.41 - C-I: 0.11 ### Step 5: Determine the Order of Bond Strength Since a greater electronegativity difference corresponds to a stronger bond, we can conclude the order of bond strength is: **C-F > C-Cl > C-Br > C-I** ### Final Answer The order of bond strength among C-F, C-Cl, C-Br, and C-I is: **C-F > C-Cl > C-Br > C-I**

To determine the order of bond strength among C-F, C-Cl, C-Br, and C-I bonds, we can analyze the electronegativity of the atoms involved and how it affects bond strength. Here’s a step-by-step solution: ### Step 1: Understand Electronegativity Electronegativity is a measure of an atom's ability to attract and hold onto electrons. The greater the difference in electronegativity between two bonded atoms, the stronger the bond tends to be due to increased ionic character. ### Step 2: Identify Electronegativity Values We need to know the electronegativity values of carbon and the halogens: - Carbon (C): 2.55 ...
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Knowledge Check

  • C-F is the strongest among C-F, C-Cl, C-Br, C-I because

    A
    the strongest bonds are formed by the overlap of orbitals of the same principle quantum number. In C-F the overlap involves orbitals of the same principle quantum number (second)
    B
    Fis the most electronegative among F, Cl, Br, I
    C
    F has the smallest size among the halides
    D
    'F' is the least electronegative
  • The correct order of C-O bond length among

    A
    `CO lt CO_(2) lt CO_(3)^(2-)`
    B
    `CO_(2) lt CO_(3)^(2-) lt CO`
    C
    `CO lt CO_(3)^(2-) lt CO_(2)`
    D
    `CO_(3)^(2-) lt CO_(2) lt CO`
  • The correct order of increasing bond length of C- H, C-O, C-C and C=C is

    A
    `C-H lt C=C lt C-O lt C-C`
    B
    `C-C lt C=C lt C-O lt C-H`
    C
    `C-O lt C-H lt C-C lt C=C`
    D
    `C-H lt C-O lt C-C lt C=C`
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