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Isostructural species are those which ha...

Isostructural species are those which have the same shape and hybridisation. Among the given identify the isostructural pairs.

A

`[NF_(3) and BF_(3)]`

B

`[BF_(4)^(-)and NH_(4)^(+)]`

C

`[BCl_(3)and BrCl_(3)]`

D

`[NH_(3)and NO_(3)^(-)]`

Text Solution

Verified by Experts

The correct Answer is:
B

`BF_(4)^(-)and NH_(4)^(+)` are isostructural species. The central atom in both is `sp^(3)` hybridised.
`BF_(4)^(-):H=^(1//2)[3+4-0+1]=4(sp^(3))`
`NH_(4)^(+):H=^(1//2)[5+4-1+0]=4(sp^(3))`
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Knowledge Check

  • Isostructrual species are those which have the same shape and hybridisation. Among the given identify the isostructural pairs.

    A
    `NH_(3)` and `BF_(3)`
    B
    `BF_(4)^(-)` and `NH_(4)^(+)`
    C
    `BCl_(3)` and `BrCl_(3)`
    D
    `NH_(3)` and `NO_(3)^(-)`
  • Isostructural species are those which have the same shape and hybridisation. Among the given species identify the isostructural pairs.

    A
    `NH_3` and `BF_3`
    B
    `BF_4^-` and `NH_4^+`
    C
    `BCI_3` and `BrCl_3`
    D
    `NH_3` and `NO_3^-`
  • Isostructural species are those which have the same shape and hybridization. Among the given species, identify the isostructural pairs .

    A
    `[NF_(3) and BF_(3)]`
    B
    `[BF_(4)^(-) and NH_(4)^(+)]`
    C
    `[BCl_(3) and BrCl_(3)]`
    D
    `[NH_(3) and NO_(3)^(-)]`
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