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The van der Waal's equation of state for...

The van der Waal's equation of state for 1 mole real gas is `(P + (a)/(V^(2))) (v - b) = RT`....(i)
The Virial equation for 1 mole real gas is `PV = RT [1 + (x)/(V) + (y)/(V^(2)) + (z)/(V^(3))+....." To higher power of " V]` ....(ii)
when x, y and z are constants which are known as 2nd, 3rd adn 4th co-efficients respectively. The temperature at which real gas obeys ideal gas equation i.e., `(PV = nRT)` is known as Boyle's temperature.
Answer the following questions on the basis of the above write up :
If equation (ii) can be one of the way of writing of equation (i), then what will be the value of y?

A

`b - (a)/(RT)`

B

`b^(2)`

C

`b^(3)`

D

`a - (RT)/(b)`

Text Solution

Verified by Experts

The correct Answer is:
B
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