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Reactions of C(6)H(5)CH(2)Br with aqueou...

Reactions of `C_(6)H_(5)CH_(2)Br` with aqueous sodium hydroxide follows:

A

`S_(N)1` mechanism

B

`S_(N)2` mechanism

C

Any of the above two depending upon the temperature of reaction

D

saytzeff rule

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The correct Answer is:
To solve the question regarding the reaction of `C6H5CH2Br` (benzyl bromide) with aqueous sodium hydroxide, we will analyze the mechanism involved in this reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are benzyl bromide (`C6H5CH2Br`) and aqueous sodium hydroxide (`NaOH`). 2. **Understand the Nature of the Reaction**: Benzyl bromide contains a bromine atom that acts as a leaving group. When it reacts with sodium hydroxide, we need to determine whether the reaction follows an SN1 or SN2 mechanism. 3. **Consider the Mechanism**: - **SN1 Mechanism**: This mechanism involves the formation of a carbocation intermediate. The leaving group (Br) departs first, forming a carbocation, which is then attacked by the nucleophile (OH⁻). - **SN2 Mechanism**: This mechanism involves a single concerted step where the nucleophile attacks the substrate as the leaving group departs. 4. **Analyze the Carbocation Stability**: In the case of benzyl bromide, when the bromine leaves, it forms a benzyl carbocation (`C6H5CH2+`). This carbocation is resonance-stabilized due to the adjacent aromatic ring, making it relatively stable. 5. **Determine the Reaction Pathway**: Given the stability of the benzyl carbocation, the reaction will favor the SN1 pathway. The bromine leaves first, forming the stable carbocation, and then the hydroxide ion (OH⁻) from the sodium hydroxide attacks the carbocation. 6. **Write the Reaction**: The overall reaction can be summarized as follows: \[ C6H5CH2Br + NaOH \rightarrow C6H5CH2OH + NaBr \] Here, benzyl alcohol (`C6H5CH2OH`) is formed as the product. ### Final Answer: The reaction of `C6H5CH2Br` with aqueous sodium hydroxide follows the **SN1 mechanism**, resulting in the formation of benzyl alcohol. ---

To solve the question regarding the reaction of `C6H5CH2Br` (benzyl bromide) with aqueous sodium hydroxide, we will analyze the mechanism involved in this reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are benzyl bromide (`C6H5CH2Br`) and aqueous sodium hydroxide (`NaOH`). 2. **Understand the Nature of the Reaction**: ...
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NCERT EXEMPLAR-HALOALKANES AND HALOARENES-Haloalkanes And Haloarenes
  1. Chloromethane on treatment with excess of ammonia yields mainly

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  2. Molecules whose mirror image is non-superimposable over them are known...

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  3. Reactions of C(6)H(5)CH(2)Br with aqueous sodium hydroxide follows:

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  4. Which of the carbon atoms present in the molecule given below are asym...

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  5. Which of the following compounds will give racemic mixture on nucleoph...

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  6. Which of the following order is correct?

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  7. Which of the following order is correct?

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  8. Which of the following order is correct?

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  9. Which of the following order is correct?

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  10. Which is the correct increasing order of boiling points

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  11. Which is the correct increasing order of boiling points of the followi...

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  12. Which of the following statements are correct about the above reaction...

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  13. Which of the following statements are correct about this reaction?

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  14. Which of the following statements are correct about the reaction inter...

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  15. Which of the following statements are correct about the mechanism of t...

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  16. Which of the following statements are correct about the kinetics of th...

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  17. Haloalkanes contain halogen atom(s) attached to the sp^(3)hybridised c...

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  18. Ethylene cghloride and ethylidene chloride are isomers. Identify the c...

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  19. Which of the following compounds are gem-dihalides?

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  20. Which of the following are secondary bromides ?

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