Home
Class 12
CHEMISTRY
Write the correct order of acidic streng...

Write the correct order of acidic strength of following compounds:
`(a)H - F " "(b) H - Cl`
`(c) H - Br" "(d)H - I `

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of acidic strength for the compounds \( H-F \), \( H-Cl \), \( H-Br \), and \( H-I \), we can follow these steps: ### Step 1: Identify the Conjugate Bases When an acid donates a proton (\( H^+ \)), it forms a conjugate base. For each of the acids given, the conjugate bases are: - For \( H-F \): The conjugate base is \( F^- \) - For \( H-Cl \): The conjugate base is \( Cl^- \) - For \( H-Br \): The conjugate base is \( Br^- \) - For \( H-I \): The conjugate base is \( I^- \) ### Step 2: Assess the Stability of the Conjugate Bases The strength of an acid is related to the stability of its conjugate base. A more stable conjugate base corresponds to a stronger acid. The stability of the conjugate bases can be influenced by the size of the atoms and the ability to disperse the negative charge. - \( F^- \) (Fluoride) is the smallest and least stable due to high electronegativity and small size. - \( Cl^- \) (Chloride) is larger than \( F^- \) and more stable. - \( Br^- \) (Bromide) is larger than \( Cl^- \) and even more stable. - \( I^- \) (Iodide) is the largest and most stable due to the ability to disperse the negative charge over a larger volume. ### Step 3: Determine the Order of Acidity Based on the stability of the conjugate bases: - \( I^- \) is the most stable, so \( H-I \) is the strongest acid. - \( Br^- \) is next, so \( H-Br \) follows. - \( Cl^- \) is less stable than \( Br^- \), so \( H-Cl \) comes next. - \( F^- \) is the least stable, making \( H-F \) the weakest acid. ### Conclusion: Order of Acidity Thus, the correct order of acidic strength from strongest to weakest is: \[ H-I > H-Br > H-Cl > H-F \] ### Final Answer The order of acidic strength is: 1. \( H-I \) 2. \( H-Br \) 3. \( H-Cl \) 4. \( H-F \)
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • GOC

    MOTION|Exercise Exercise - 4 Level - I|13 Videos
  • GOC

    MOTION|Exercise Exercise - 4 Level - II|14 Videos
  • GOC

    MOTION|Exercise Exercise - 2 (Level - II)|114 Videos
  • GASEOUS STATE

    MOTION|Exercise EXERCISE-4( LEVEL-II)|19 Videos
  • GRIGNARD REAGENT

    MOTION|Exercise EXERCISE-2|16 Videos

Similar Questions

Explore conceptually related problems

Write correct order of acidic strength of following compounds:

Write correct order of acidic strength of following compounds: .

Knowledge Check

  • The correct order of strength of H-bond in the following compound :

    A
    `H_(2)O gt H_(2)O_(2) gt HF gt H_(2)S`
    B
    `HF gt H_(2)O_(2) gt H_(2)O_(2) gt H_(2)S`
    C
    `HF gt H_(2)O gt H_(2)S gt H_(2)O_(2)`
    D
    `HF gt H_(2)O gt H_(2)O_(2) gt H_(2)S`
  • The correct order of strength of H- bond in the following compound :

    A
    `H_(2)O gt H_(2)O_(2) gt HF gt H_(2)S`
    B
    `HF gt H_(2)O_(2) gt H_(2)O gt H_(2)S`
    C
    `HF gt H_(2)O gt H_(2)S gt H_(2)O_(2)`
    D
    `HF gt H_(2)O gt H_(2)O_(2) gt H_(2)S`
  • The correct order of the strength of H-bonds is :

    A
    `H….FgtH….OgtH…..N`
    B
    `H….NgtH….OgtH….F`
    C
    `H….OgtH….NgtH….F`
    D
    `H….FgtH….NgtH….O`
  • Similar Questions

    Explore conceptually related problems

    Write the correct order of acidic strength of following compounds: (a)CH_(4)" "(b)NH_(3) (c)H_(2)O" "(d)H-F

    Write the correct order of acidic strength of following compounds: (a)F - CH_(2) - CH_(2) - O-H" "(b) NO_(2)- CH_(2)-CH_(2)-O-H (c) Br - CH_(2) - CH_(2) - O-H" "(d) overset(o+)(NH_(3))- CH_(2) - CH_(2) -O - H

    Write the correct order of acidic strength of following compounds: (a)CH_(3)COOH" "(d)CH_(3)CH_(2)OH (c )C_(6)H_(5)OH" "(d)C_(6)H_(5)SO_(3)H

    Write correct order of acidic strength of following compounds: (a) NO_(2) - CH_(2) - overset(O)overset(||)C - O - H (b) F - CH_(2) - overset(O)overset(||)C - O - H (c) Ph - CH_(2) - overset(O)overset(||)C - O - H (d) CH_(3) - CH_(2) - overset(O)overset(||)C - O - H

    The correct order of the strength of H-bonds is :