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Give possible explanation for the follow...

Give possible explanation for the following : (i) Cyclohexanone forms cyanohydrins in good yield but 2,2,6 trimethyl-cyclohexanone does not .

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To explain why cyclohexanone forms cyanohydrins in good yield while 2,2,6-trimethylcyclohexanone does not, we can analyze the reactions and the structural differences between the two compounds. ### Step-by-Step Solution: 1. **Understanding the Reactivity of Cyclohexanone**: - Cyclohexanone (C6H10O) is a simple cyclic ketone with a carbonyl group (C=O) that is relatively accessible for nucleophilic attack. - When treated with cyanide ion (CN-), it undergoes nucleophilic addition to form a cyanohydrin. ...
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Giving plausible explanation for each of the following: i. Cyclohexanone forms cyanohydrin good yield but 2,2,6-trimethylcyclohexanone does not. ii. There are two (-NH_(2)) groups in semicarbazide. However, only one is involved in the formation of semicarbazones. iii. During the preparation of esters from a carboxylic acid and an alcohol in the ester should be removed as soon as it is formed.

(a) Give a plausible expianation for each one of the following : - (i) There are two - NH_(2) groupsin semicarbazide. However, only one such group is involvedin the formation of semicarbazones. (ii) Cyclohexanone forms cyanohydrin in good yield but 2,4,6 -trimethylcyclohexanone does not. (b) An organic compound with molecular formula C_(9)H_(10)O forms, 2,4 - DNP derivative, reduces Tollens' reagent and undergoes Cannizzaro reaction. On vigorous oxidation it gives 1,2-benzene-di-carboxylic acid. Identify the compound.

Which of the following compound will react with cyclohexanone to form an enamine ?

Which of the following amines will react with cyclohexanone to give enamine?

Which of the following reactions would give a good yield of hydrocarbon product ?

CBSE COMPLEMENTARY MATERIAL-ALDEHYDES,KETONES AND CARBOXYLIC ACIDS-SHORT ANSWER -I TYPE QUESTIONS (2 MARKS)
  1. Which acid of each pair shown here would you expect to be stronger ? C...

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  2. Which acid of each pair shown here would you expect to be stronger ? .

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  3. Carboxylic acids do not give reactions of aldehydes and ketones why ?

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  4. Write IUPAC name of the following : .

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  5. Write IUPAC name of the following : .

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  6. Accout for the following : (i) Oxidation of toluence to C(6)H(5)CHO wi...

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  7. Accout for the following : (ii) Melting point of an acid with even num...

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  8. Distinguish between : (i) C(2)H(5)OH and CH(3)CHO.

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  9. Distinguish between : (ii) C(6)H(5)COCH(3) and C(6)H(5)CH(2)CHO.

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  10. Complete the following reactions by identitying A: A+ "Hydrogen" (g)...

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  11. Compelte the following reactions by identifying B and C: (ii) CH(3)-ov...

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  12. Benzaldehyde gives a positive test with Tollen's reagent but not with ...

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  13. Aldehydes usually do not form stable hydrates but chloral normally exi...

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  14. Give possible explanation for the following : (i) Cyclohexanone forms ...

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  15. Give possible explanation for the following : (ii) There are two - NH2...

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  16. Aldehydes are easily oxidisable yet propanal can conveniently br prepa...

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  17. Do the following conversions in not more than two steps. (i) Benzoic a...

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  18. Write the reactions involved in the following reactions: (i) Clemmen...

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  19. Convert the following (i) Ethyl benzene to benzoic acid

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  20. Convert the following (ii) Ethanal to but-2-enal.

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