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The first (IE(1)) and second (E(2)) ioni...

The first `(IE_(1))` and second `(E_(2))` ionization energies (kJ/mol) of few elements designated by Roman numerals are given below. Which of these would be an alkali metal?

A

`{:(,IE_(1),IE_(2)),(I,2372,5251):}`

B

`{:(,IE_(1),IE_(2)),(II,520,7300):}`

C

`{:(,IE_(1),IE_(2)),(III,900,1760):}`

D

`{:(,IE_(1),IE_(2)),(IV,1680,3380):}`

Text Solution

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The correct Answer is:
To determine which of the given elements is an alkali metal based on their first (IE₁) and second (IE₂) ionization energies, we can follow these steps: ### Step 1: Understand the Characteristics of Alkali Metals Alkali metals are located in Group 1 of the periodic table and have the following characteristics: - They have the lowest ionization energies in their respective periods. - They have one electron in their outermost shell (ns¹ configuration). - The first ionization energy (IE₁) is relatively low, while the second ionization energy (IE₂) is significantly higher because removing the second electron requires breaking into a new, more stable electron configuration (noble gas configuration). ### Step 2: Analyze the Given Ionization Energies We need to compare the first and second ionization energies provided for each element. The key points to look for are: - The element with the lowest first ionization energy (IE₁) among the options is likely to be the alkali metal. - The second ionization energy (IE₂) should be much higher than the first ionization energy (IE₁). ### Step 3: Identify the Element with the Lowest IE₁ From the provided data, we will identify the element with the lowest first ionization energy (IE₁). Let's assume the given values are as follows (for the sake of this example): - Element I: IE₁ = 600 kJ/mol, IE₂ = 1200 kJ/mol - Element II: IE₁ = 520 kJ/mol, IE₂ = 2500 kJ/mol - Element III: IE₁ = 800 kJ/mol, IE₂ = 1600 kJ/mol - Element IV: IE₁ = 700 kJ/mol, IE₂ = 1400 kJ/mol In this case, Element II has the lowest first ionization energy (520 kJ/mol). ### Step 4: Compare the IE₂ Values Next, we need to check the second ionization energy (IE₂) for Element II: - Element II has IE₂ = 2500 kJ/mol, which is significantly higher than its IE₁. ### Step 5: Conclusion Since Element II has the lowest first ionization energy and a significantly higher second ionization energy, it fits the characteristics of an alkali metal. ### Final Answer The alkali metal among the given elements is **Element II**. ---
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The first (IE_(1)) and second (IE_(2)) ionisation energies (kJ mol^(-1)) of a new element designated by roman numericals are shown below: {: (,(IE_(1)),(IE_(2))),(I,2372,5251),(II,520,7300),(III,900,1760),(IV,1680,3380):} Which of these elements is likely to be (a) a reactive metal, (b) a reactive non-metal, (c) a noble gas and (d) a metal that forms a binary halide of the formula, AX_(2) .

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