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Magnetic moment of [Cu(NH(3))(4)]^(2+) i...

Magnetic moment of `[Cu(NH_(3))_(4)]^(2+)` ion is

A

2.83, tetrahedral

B

1.73, tetrahedral

C

2.83, square planar

D

1.73, square planar

Text Solution

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The correct Answer is:
D
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(i) Predict the geometry of [NiCN_(4)]^(2-) (ii) Calculate the spin only magnetic moment of [Cu(NH_(3))_(4)]^(2+) ion.

Explain the geometry of [Cu(NH_(3))_(4)]^(2+) on the basis of hybridisation . [At. No. Cu=2_(9) ]

Knowledge Check

  • Hybridization and magnetic moment of [Cu(NH_(3))_(4)]^(2+) and [Mn(CN)_(6)^(3-) ions respectively are

    A
    `dsp^(2), 1.73BM: d^(2)sp^(3), 2.83 BM`
    B
    `sp^(3),zero, sp^(3)d^(2), 4.9BM`
    C
    `sp^(3), 1.73 BM, sp^(3)d^(2), 4.9BM`
    D
    `dsp^(2), 1.73 BM, d^(2)sp^(3), zero`

  • The magnetic moments of [Cu(NH_(3))_(4)]^(2+) was found to be 1.73 B.M. The number of unpaired electrons in the complex is:

    A
    0
    B
    1
    C
    2
    D
    3

  • The shape of [Cu(NH_(3))_(4)]^(2+) is

    A
    tetrahedral
    B
    square planar
    C
    pyramidal
    D
    octahedral

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    The magnetic moment of [NiX_(4)]^(2-) ion is found to be zero. Then the ion is : (X=monodentate anionic ligand)

    The magnetic moment of [NiX_(4)]^(2-) ion is found to be zero. Then the ion is : (X=monodentate anionic ligand)

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