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1.6 g of an organic compound gave 2.6 g ...

1.6 g of an organic compound gave 2.6 g of magnesium pyrophosphate . The percentage of phosphorus is the compound is

A

`45.38%`

B

`54.38`

C

`37.76%`

D

`19.02%`

Text Solution

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The correct Answer is:
To find the percentage of phosphorus in the organic compound, we can follow these steps: ### Step 1: Identify the mass of the organic compound and magnesium pyrophosphate. - Mass of the organic compound = 1.6 g - Mass of magnesium pyrophosphate (Mg2P2O7) = 2.6 g ### Step 2: Calculate the molar mass of magnesium pyrophosphate (Mg2P2O7). - Molar mass of magnesium (Mg) = 24 g/mol - Molar mass of phosphorus (P) = 31 g/mol - Molar mass of oxygen (O) = 16 g/mol The formula for magnesium pyrophosphate is Mg2P2O7, which contains: - 2 magnesium atoms - 2 phosphorus atoms - 7 oxygen atoms Calculating the molar mass: \[ \text{Molar mass of Mg2P2O7} = (2 \times 24) + (2 \times 31) + (7 \times 16) \] \[ = 48 + 62 + 112 = 222 \text{ g/mol} \] ### Step 3: Determine the total mass of phosphorus in magnesium pyrophosphate. Since there are 2 phosphorus atoms in the formula Mg2P2O7: \[ \text{Mass of phosphorus in Mg2P2O7} = 2 \times 31 = 62 \text{ g} \] ### Step 4: Calculate the percentage of phosphorus in magnesium pyrophosphate. The percentage of phosphorus in magnesium pyrophosphate can be calculated using the formula: \[ \text{Percentage of phosphorus} = \left( \frac{\text{Mass of phosphorus}}{\text{Molar mass of Mg2P2O7}} \right) \times 100 \] Substituting the values: \[ \text{Percentage of phosphorus} = \left( \frac{62}{222} \right) \times 100 \approx 27.93\% \] ### Step 5: Calculate the mass of phosphorus in the organic compound. Using the mass of magnesium pyrophosphate produced (2.6 g): \[ \text{Mass of phosphorus in the organic compound} = \text{Percentage of phosphorus} \times \text{Mass of Mg2P2O7} \] \[ = 0.2793 \times 2.6 \approx 0.726 \text{ g} \] ### Step 6: Calculate the percentage of phosphorus in the organic compound. Finally, we can find the percentage of phosphorus in the organic compound: \[ \text{Percentage of phosphorus in the organic compound} = \left( \frac{\text{Mass of phosphorus in organic compound}}{\text{Mass of organic compound}} \right) \times 100 \] \[ = \left( \frac{0.726}{1.6} \right) \times 100 \approx 45.38\% \] ### Final Answer: The percentage of phosphorus in the organic compound is approximately **45.38%**. ---
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